1. Metal-free amino-graphdiyne for applications in electrocatalytic hydrogen evolution.
- Author
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He, Feng, Xing, Chengyu, and Xue, Yurui
- Subjects
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ELECTROCATALYSIS , *ELECTROCATALYSTS , *HYDROGEN evolution reactions , *CATALYTIC activity , *BASE catalysts , *MOLECULAR dynamics , *HYDROGEN , *DENSITY functional theory - Abstract
[Display omitted] • A new graphdiyne based metal-free catalyst was successfully synthesized. • The catalyst triggered highly catalytic performances toward hydrogen evolution. • The unique nanostructure guaranteed the fast proton-electron transfer during HER. • The alkyne-alkene transition induced the excellent catalytic activity of TAGDY. Graphdiyne-based metal-free catalysts demonstrate outstanding performances in electrocatalysis. In order to accurately understand the activity origin of metal-free electrocatalytic hydrogen production at the atomic level, we have successfully designed and prepared a new metal-free catalyst of 1,2,4-triamino-graphdiyne (TAGDY). Structural characterizations showed that TAGDY has unique nanostructure, which guarantees the fast proton-electron transfer during the catalytic process. Experimental studies revealed that TAGDY possesses excellent electrocatalytic activities and long-term durability towards hydrogen evolution in acidic conditions, better than the most reported metal-free electrocatalysts. Density functional theory calculations and Born-Oppenheimer molecular dynamics simulations revealed that the interaction of (H++e−) pair with alkyne bond induces the transition between C C and C C in TAGDY, which effectively enhanced the catalytic activities of initial inert carbon sites. Combination of theory and experiment as well as the structural characterization, a new level of knowledge for the activity origin and catalytic mechanism of graphdiyne-based metal-free electrocatalysts are presented. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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