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Biochar is a well-known carbon material with diversified functionalities and excellent physicochemical characteristics with high wastewater treatment potential. This review aims to summarize recent advancements in the development of biochar and biochar-based nanohybrid materials as a potential tool for the removal of harmful organic compounds such as synthetic dyes/effluents. The formation of biochar using pyrolysis of renewable feedstocks and their applications in various industries are explained hereafter. The characteristics and construction of biochar-based hybrid materials are explained in detail. Diversity of feedstocks, including municipal wastes, industrial byproducts, agricultural, and forestry residues, endows different biochar types with a wide structural variety. The production of cost-effective biochar drives the interest in manipulating biochars and induces desire functionality using nanoscale reinforcements. Various types of biochars, such as magnetic biochar, layered nanomaterial coated biochar, nanometallic oxide composites, chemically and physically functionalized biochar, have been produced. With the aid of nanomaterial, hybrid biochar exhibits a high potential to remove toxic contaminants. Depending upon biochar type, dyes/effluents can be removed via different mechanisms, including the Fenton process, photocatalytic degradation, π–π interaction, electrostatic interaction, and physical adsorption. In conclusion, desired physicochemical features, and tunable surface properties of biochar present high potential material in removing organic dyes and other effluents. The blended biochar with different materials/nanomaterials endows broader development and multi-functional opportunities for treating dyes/effluents. [Display omitted] • Biochar-based nanohybrids, as trendy materials, are reviewed. • The characteristic rendering biochar matrices for environmental settings are given. • The work spotlight the efficient treatment of hazardous contaminants using biochar-based nanohybrids. [ABSTRACT FROM AUTHOR]

Abstract In recent years, owing to the serious ecological risks and human health-related adverse effects, the wide occurrence of hazardous contaminants along with their potential to enter the environment have gained great public concerns. In this context, significant actions are urgently required to tackle the ignorance and inefficient monitoring/removal of emerging/(re)-emerging contaminants (ECs) in the environment from different routes of concerns, i.e., industrial waste, pharmaceutical, personal care products (PCPs), toxic effluents, etc. Laccases are multinuclear copper-containing oxidoreductases and can carry out one electron oxidation of a broad spectrum of environmentally related contaminants. In biotechnology, this group of versatile enzymes is known as a green catalyst/green tool with enormous potentialities to tackle ECs of high concern. In this review, we endeavored to present up-to-date literature concerning the potential use of immobilized laccases for the degradation and remediation of various types of environmental pollutants present in the environment. Both, pristine and immobilized, laccases have shown great capacity to oxidative degradation and mineralization of endocrine disrupting chemicals (EDs) in batch treatment processes as well as in large-scale continuous reactors. These properties make laccase as particularly attractive biocatalysts in environmental remediation processes, and their use might be advantageous over the conventional treatments. This review summarizes the most significant recent advances in the use of laccases and their future perspectives in environmental biotechnology. Graphical abstract Image 1086 Highlights • Emerging contaminants (ECs) in the environment and their laccase-assisted degradation is reviewed. • Significant actions are required to avoid the ignorance and inefficient ECs removal. • New strategies are needed to control the ECs in the environment from different routes of concerns. • Laccase has emerged as green catalyst with enormous potentialities to tackle ECs of high concern. [ABSTRACT FROM AUTHOR]