1. Two-dimensional NMR spectroscopy of 13C methanol at less than 5 μT.
- Author
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Shim, Jeong Hyun, Lee, Seong-Joo, Hwang, Seong-min, Yu, Kwon-Kyu, and Kim, Kiwoong
- Subjects
- *
NUCLEAR magnetic resonance spectroscopy , *METHANOL , *MAGNETIC fields , *COMPRESSED sensing , *ANALYTICAL chemistry - Abstract
Two-dimensional (2D) spectroscopy is one of the most significant applications of nuclear magnetic resonance (NMR). Here, we demonstrate that the 2D NMR can be performed even at a low magnetic field of less than 5 μT, which is ten times less than the Earth’s magnetic field. The pulses used in the experiment were composed of circularly polarized fields for coherent as well as wideband excitations. Since the excitation band covers the entire spectral range, the simplest two-pulse sequence delivered the full 2D spectrum. At 5 μT, methanol with 13 C enriched up to 99% belongs to a strongly coupled regime, and thus its 2D spectrum exhibits complicated spectral correlations, which can be exploited as a fingerprint in chemical analysis. In addition, we show that, with compressive sensing, the acquisition of the 2D spectrum can be accelerated to take only 45% of the overall duration. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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