1. Dispersion of carbon nanotubes by carbazole-tailed amphiphilic imidazolium ionic liquids in aqueous solutions
- Author
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Dong, Bin, Su, Yijin, Liu, Yonghui, Yuan, Jie, Xu, Jingkun, and Zheng, Liqiang
- Subjects
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DISPERSION (Chemistry) , *CARBON nanotubes , *CARBAZOLE , *POLYCYCLIC aromatic hydrocarbons , *IMIDAZOLES , *IONIC liquids , *SOLUTION (Chemistry) , *SURFACE active agents , *ADSORPTION (Chemistry) , *FLUORESCENCE - Abstract
Abstract: Surfactants with a polycyclic aromatic moiety and a long hydrocarbon chain, carbazole-tailed amphiphilic imidazolium ionic liquids 1-[n-(N-carbazole)alkyl]-3-methylimidazolium bromide [CzC n MIm]Br (n =10 and 12), were designed to disperse carbon nanotubes (CNTs) in aqueous solutions. UV–vis–NIR spectra were performed to determine the dispersion of CNTs and the optimal concentration (C opt) of [CzC n MIm]Br. Compared with [C n MIm]Br, [CzC n MIm]Br was more effective with the smaller C opt and more individual CNTs, reflecting the effect of the carbazole moiety. The adsorption of [CzC n MIm]Br molecules on CNTs was investigated by zeta-potential, surface tension, fluorescence, and 1H NMR. Having zeta-potentials higher than 15mV contributed to the long-term stability of aqueous CNT dispersions. The significant fluorescence quenching and the upfield shift of carbazole protons support the π–π stacking interaction between carbazole moieties and the π-networks of CNTs. Meanwhile, the upfield shift of imidazolium protons indicates the cation–π interaction between the imidazolium ions and the π-networks of CNTs. [Copyright &y& Elsevier]
- Published
- 2011
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