1. Novel organic base-immobilized magneto-polymeric nanospheres as efficient Pickering interfacial catalyst for transesterification.
- Author
-
Tang, Jun, Zhang, Qi, Hu, Kecheng, Cao, Shixiong, Zhang, Shouhao, and Wang, Jianli
- Subjects
- *
CATALYSTS , *TRANSESTERIFICATION , *CATALYSIS , *TEMPERATURE , *NANOPARTICLES - Abstract
Graphical abstract Highlights • Fe 3 O 4 @PS-TMG was synthesized by immobilizing TMG onto the shell of nanohybrids. • The loading of TMG as well as surface property of catalyst can be well regulated. • The MPIC can stabilize soybean oil-in-methanol Pickering emulsion. • The MPIC exhibited higher catalytic activity for transesterification. Abstract A novel magnetic Pickering interfacial catalyst (MPIC) was developed and used for highly effective and clean production of biodiesel. The catalyst was synthesized by immobilization of 1,1,3,3-tetramethylguanidine (TMG) onto the shell of Fe 3 O 4 @Chloromethyl PS nanohybrids. The resultant Fe 3 O 4 @PS-TMG was measured by transmission electron microscope (TEM), dynamic lighting scattering (DLS), Fourier transform infrared spectroscopy (FTIR), elemental analysis (EA), thermogravimetric analysis (TG), contact angles (CA). The results showed that surface property and TMG loading of catalyst can be finely regulated via adjusting the feeding of TMG. Fe 3 O 4 @PS-TMG with amphiphilic surface can stabilize soybean oil-in-methanol Pickering emulsion, which would offer large interfacial area and surface enrichment of reactants, leading to a significant enhancement of such liquid-liquid (L-L) biphasic reaction with high mass transfer resistance. Furthermore, the MPIC can be facile separated from the mixture of reaction by magnet, and showed excellent stability over 5 recycles. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
- View/download PDF