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Recently some special type of mixed alphabet codes that generalize the standard codes has attracted much attention. Besides Z 2 Z 4 -additive codes, Z 2 Z 2 [ u ] -linear codes are introduced as a new member of such families. In this paper, we are interested in a new family of such mixed alphabet codes, i.e., codes over Z 2 Z 2 [ u 3 ] where Z 2 [ u 3 ] = { 0 , 1 , u , 1 + u , u 2 , 1 + u 2 , u + u 2 , 1 + u + u 2 } is an 8-element ring with u 3 = 0 . We study and determine the algebraic structures of linear and cyclic codes defined over this family. First, we introduce Z 2 Z 2 [ u 3 ] -linear codes and give standard forms of generator and parity-check matrices and later we present generators of both cyclic codes and their duals over Z 2 Z 2 [ u 3 ] . Further, we present some examples of optimal binary codes which are obtained through Gray images of Z 2 Z 2 [ u 3 ] -cyclic codes. [ABSTRACT FROM AUTHOR]