1. Bimetallic mutual-doping magnetic aerogels for iodine reduction capture and immobilization.
- Author
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Zhou, Xin-Yu, Chen, Kai-Wei, Gu, Ao-tian, Yun, Shan, Mao, Ping, Yang, Yi, and Chen, Jing
- Subjects
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IRON oxides , *COPPER , *BIMETALLIC catalysts , *AEROGELS , *RADIOACTIVE decay , *IODINE isotopes , *OXYGEN carriers , *GELATION - Abstract
Based on the in-situ bimetallic co-gelation process, the high dispersion of Cu in the Cu/Fe 3 O 4 -BMMA was realized, providing conditions for the efficient elimination of I 2. The adsorption experiments showed that Cu/Fe 3 O 4 -BMMA has good I 2 adsorption capacity (631.3 mg/g) and fast capture kinetics (equilibrium time <30 min). In addition, Cu/Fe 3 O 4 -BMMA was able to effectively remove trace I 2 in the solution from ppm level (1.0 ppm) down to ppb level (≤30 ppb). The adsorbed I 2 was converted into stable CuI, avoiding secondary pollution due to desorption. Notably, the used Cu/Fe 3 O 4 -BMMA was able to be separated from the solution by simple magnetic suction, which greatly improved the efficiency and reduced the recovery cost. Overall, this study provides a potentially efficient iodine capture material for long-term decay storage of radioactive iodine. [Display omitted] • The Cu in Cu/Fe 3 O 4 -BMMA exhibited high reactivity and utilization. • Cu/Fe 3 O 4 -BMMA can effectively reduce I 2 and adsorb it to generate stable CuI. • Cu/Fe 3 O 4 -BMMA exhibited a high removal rate of trace I 2 in actual environments. • The used adsorbents can be rapidly recovered by magnetic adsorption. Adsorption is considered to be one of the most effective methods to remove radioiodine from the solution. However, developing highly efficient adsorbents and the rapid recovery of the used adsorbents is still a challenge. Here, a series of Cu/Fe 3 O 4 bimetallic mutual-doping magnetic aerogels (Cu/Fe 3 O 4 -BMMA) were synthesized. Based on the in-situ bimetallic co-gelation process, the high dispersion of Cu in the aerogel was realized, providing conditions for the efficient elimination of I 2. The Fe3+ in the initial gel was reduced to magnetic Fe 3 O 4 during the preparation process, allowing for the quick recovery of the adsorbent through the application of a magnetic field. The adsorption experiments showed that Cu/Fe 3 O 4 -BMMA has good I 2 adsorption capacity (631.3 mg/g) and fast capture kinetics (equilibrium time < 30 min). In addition, Cu/Fe 3 O 4 -BMMA was able to effectively remove trace I 2 in the solution from ppm level (1.0 ppm) down to ppb level (≤30 ppb). The adsorbed I 2 was converted into stable CuI, avoiding secondary pollution due to desorption. Overall, this study provides a potentially efficient iodine capture material for long-term decay storage of radioactive iodine. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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