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This study investigates—for the first time—the synthesis of a novel Ca-rich biochar (N–Ca–B) and its potential use for phosphorus (P) recovery from both synthetic solutions (SS) and treated urban wastewater (TUW) in a continuous stirring tank reactor (CSTR) mode. The novel biochar was synthesized by pyrolysis at 900 °C of a mixture composed of three different materials: animal biomass (poultry manure; PM), lignocellulosic waste (date palm fronds; DPFs), and abundant mineral waste (waste marble powder; WMP). Characterization of N–Ca–B showed that it has good textural properties: well-developed porosity, and high specific surface area. Furthermore, high calcium hydroxide (Ca(OH) 2) and calcium oxides (CaO) nanoparticle loads were observed on the biochar surface. The dynamic CSTR assays indicated that the P recovery efficiency mainly depended on the biochar mass, P influent concentration, and, especially, the Ca content of the feeding solution. Owing to its richness in Ca cations, TUW exhibited the highest adsorbed P amount (109.2 mg g−1), i.e., about 14% larger than the SS. P recovery occurs through precipitation as hydroxyapatite, surface complexation, and electrostatic interactions with positively charged biochar particles. In real-world scenarios, CSTR systems can be applied as a tertiary treatment step in existing wastewater treatment plants (WWTPs). Decanted P-loaded biochar can be used in agriculture as a slow-release fertilizer instead of commercial products. [Display omitted] • Waste marble powder used for calcium-rich biochar synthesis. • Ca-rich biochar has interesting physico-chemical properties. • Ca-rich biochar efficiently recovers phosphorus in CSTR mode. • Ca-rich biochar recovers high phosphorus amounts from wastewater. • Proposed approach promotes sustainability and circular economy. [ABSTRACT FROM AUTHOR]

Phosphorus (P) represents a major pollutant of water resources and at the same time a vital element for human and plants. P recovery from wastewaters and its reuse is a necessity in order to compensate the current important depletion of P natural reserves. The use of biochars for P recovery from wastewaters and their subsequent valorization in agriculture, instead of synthetic industrial fertilizers, promotes circular economy and sustainability concepts. However, P retention by pristine biochars is usually low and a modification step is always required to improve their P recovery efficiency. The pre- or post-treatment of biochars with metal salts seems to be one of the most efficient approaches. This review aims to summarize and discuss the most recent developments (from 2020- up to now) in: i) the role of the feedstock nature, the metal salt type, the pyrolysis conditions, and the experimental adsorption parameters on metallic-nanoparticles-loaded biochars properties and effectiveness in recovering P from aqueous solutions, as well as the dominant involved mechanisms, ii) the effect of the eluent solutions nature on the regeneration ability of P-loaded biochars, and iii) the practical challenges facing the upscaling of P-loaded biochars production and valorization in agriculture. This review shows that the synthesized biochars through slow pyrolysis at relatively high temperatures (up to 700–800 °C) of mixed biomasses with Ca– Mg-rich materials or impregnated biomasses with specific metals in order to from layered double hydroxides (LDHs) biochars composites exhibit interesting structural, textural and surface chemistry properties allowing high P recovery efficiency. Depending on the pyrolysis's and adsorption's experimental conditions, these modified biochars may recover P through combined mechanisms including mainly electrostatic attraction, ligand exchange, surface complexation, hydrogen bonding, and precipitation. Moreover, the P-loaded biochars can be used directly in agriculture or efficiently regenerated with alkaline solutions. Finally, this review emphasizes the challenges concerning the production and use of P-loaded biochars in a context of circular economy. They concern the optimization of P recovery process from wastewater in real-time scenarios, the reduction of energy-related biochars production costs and the intensification of communication/dissemination campaigns to all the concerned actors (i.e., farmers, consumers, stakeholders, and policymakers) on the benefits of P-loaded biochars reuse. We believe that this review is beneficial for new breakthroughs on the synthesis and green application of metallic-nanoparticles-loaded biochars. [Display omitted] • Biochars usually have low phosphorus contents limiting their use in agriculture. • Raw biochars exhibit low phosphorus adsorption yields. • Loading biochars with nanomaterials improve their P recovery capacities. • Mixing biomasses with Ca– Mg-rich materials is an interesting option. • Biochars decoration with LDHs permits high P recovery efficiency. [ABSTRACT FROM AUTHOR]

Lead removal from aqueous solutions by raw cypress ( Cupressus sempervirens L.) sawdust (RCS) and its derivative magnesium pretreated biochar (Mg-B) was investigated under static and dynamic conditions through batch and column assays. The Hydrus-1D model was used to estimate the transport parameters of the lead measured breakthrough curves. The batch experiments results showed that Mg-B was very efficient in removing lead compared to RCS and several other previously tested natural and modified materials. The column experiments results indicated that for both RCS and Mg-B, lead breakthrough curves and the related removal efficiencies were mainly dependent on the used initial concentration and the adsorbents bed height. The use of Hydrus-1D showed that the two-site chemical non-equilibrium model describes better the experimental lead breakthrough curves for both RCS and Mg-B as the equilibrium model. [ABSTRACT FROM AUTHOR]

During the last decade, biochars have been considered as attractive and eco-friendly materials with various applications including wastewater treatment, energy production and soil amendments. However, the important nitrogen losses during biochars production using the pyrolysis process have limited their potential use in agriculture as biofertilizer. Therefore, it seems necessary to enrich these biochars with nitrogen sources before their use in agricultural soils. This paper is the first comprehensive review on the assessment of biomass type and the biochars' properties effects on N recovery efficiency from aqueous solutions as well as its release and availability for plants when applying the N-enriched chars in soils. In particular, the N recovery efficiency by raw biochars versus the type of the raw feedstock is summarized. Then, correlations between the adsorption performance and the main physico-chemical properties are established. The main mechanisms involved during ammonium (NH 4 –N) and nitrates (NO 3 –N) recovery process are thoroughly discussed. A special attention is given to the assessment of the biochars physico-chemical modification impact on their N recovery capacities improvement. After that, the application of these N-enriched biochars in agriculture and their impacts on plants growth as well as methane and nitrous oxide greenhouse gas emissions reduction are also discussed. Finally, the main future development and challenges of biochars enrichment with N from wastewaters and their valorization as biofertilizers for plants growth and greenhouse gas (GHG) emissions reduction are provided. This systematic review is intended to promote the real application of biochars for nutrients recovery from wastewaters and their reuse as eco-friendly fertilizers. [Display omitted] • Biochars have low nitrogen contents which limit their use in agriculture. • Biochars hybrid modifications allow high recovery yields of ammonium and nitrates. • N-laden biochars promote the seedling stage and the vegetative growth. • N-enriched biochars significantly reduce the N 2 O and CH 4 emissions. • N-enriched biochars promote sustainability and circular economy concepts. [ABSTRACT FROM AUTHOR]

In this study, lead removal from aqueous solutions using biochar derived from olive mill solid and liquid wastes has been investigated by applying batch experiments and geochemical modelling. The batch adsorption experiments included the assessment of several key parameters such as the contact time (kinetic), initial concentration (isotherm), pH, adsorbent dose, and the presence of competitive cations, whilst the geochemical modelling focused on the involved adsorption mechanisms using the PHREEQC code. The kinetic studies showed that lead adsorption is a relatively fast process, where intraparticle diffusion is the rate-limiting step. Biochar dose, solution pH and the presence of competitive ions significantly affected the Pb adsorption effectiveness by the biochar. Especially the higher Pb removal percentages were observed in mono-elemental solutions with high biochar dose at mildly acidic solution pH values. The maximum Pb adsorption capacity of biochar was estimated as 40.8 mg g−1 which is higher than various biochars derived from sludge, lignocellulosic and animal biomasses. On the other hand, the geochemical modelling employing the PHREEQC code showed that ion exchange and Pb precipitation are the main reactions controlling its removal from aqueous solutions, whilst surface complexation is insignificant, mainly due to the low surface functional groups on the used biochar. • Utilise olive mill solid waste (OMSW) biochar to remove Pb from aqueous solutions. • Batch sorption experiments described by Elovich kinetic equation and Sips isotherm model. • Modelling sorption process using the PHREEQC code. • Ion-exchange and precipitation were found as the key retention mechanisms of Pb. • OMSW biochar can be applied as a cost-effective and environmentally friendly sorbent. [ABSTRACT FROM AUTHOR]

Semi-arid agricultural soils have increasingly been subjected to urban sewage sludge (USS) applications due to accelerated soil depletion and shortages in manure supply. Research studies addressing USS reuse have mostly been conducted in cropping systems and focused on changes in topsoil properties of a given texture. Therefore, sludge-soil interactions could be largely influenced by the presence of plants, soil particle composition and depth. In this field study, two agricultural soils (sandy, S and sandy loam, SL) received simultaneously four annual USS applications of 40, 80, and 120 t ha−1 year−1 in absence of vegetation. Outcomes showed the increase of carbon and macronutrients in both soils proportionally to USS dose especially in the topsoil profile (0–20 cm). Subsoil (20–40 cm) was similarly influenced by sludge rates, showing comparable variations of fertility parameters though at significant lower levels. The depth-dependent improvement of soil fertility in both layers enhanced the microbiological properties accordingly, with significant variations in soil SL characterized by a higher clay content than soil S. Besides, positive correlations between increases in sludge dose, salinity, trace metals, and enzyme activities in both soils indicate that excessive sludge doses did not cause soil degradation or biotoxic effects under the described experimental conditions. In particular and despite high geoaccumulation indices of Ni in both soils and profiles, the global concentrations of Cu, Ni, Pb, and Zn were still below threshold levels for contaminated soils. In addition, the maintenance of pH values within neutral range and the increase of organic matter content with respect to control would have further reduced metal availability in amended soils. Therefore, we could closely investigate the effects of texture and depth on the intrinsic resilience of each soil to cope with repetitive USS applications. • Repetitive sludge applications changed soil properties in a dose-dependent manner. • Little variation in clay content influenced largely light-textured soil properties. • Topsoil samples had higher fertility and biological activities than subsoils. • Excessive sludge doses did not provoke soil contamination or degradation. • Absence of plants highlighted closely soil-sludge interactions on the long-term. [ABSTRACT FROM AUTHOR]