1. In-situ fabrication of manganese ferrite grafted polyaniline nanocomposite: A magnetically reusable visible light photocatalyst and a robust electrode material for supercapacitor.
- Author
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Somasundaram, Annette Jayam, Xiao, Huifang, Pandiyarajan, Sabarison, Liao, Ai-Ho, Lydia, Sharmila, and Chuang, Ho-Chiao
- Subjects
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SUPERCAPACITOR electrodes , *POLYANILINES , *VISIBLE spectra , *FACE centered cubic structure , *NANOCOMPOSITE materials , *MALACHITE green , *FERRITES - Abstract
[Display omitted] Herein, we reported the in-situ preparation of manganese ferrite (MnFe 2 O 4) grafted polyaniline (Pani), a magnetic nanocomposite for the potential visible light photocatalytic material as well as electrode material for supercapacitor. The physical characterization of the prepared nanoparticle and nanocomposite was examined with various spectroscopic and microscopic analyses. The peaks observed in the X-ray diffraction study confirm the face-centered cubic phase of MnFe 2 O 4 nanoparticles with a grain size of ∼17.6 nm. The surface morphology analysis revealed the uniform distribution of spherical-like MnFe 2 O 4 nanoparticles on the surface of Pani. The degradation of malachite green (MG) dye under exposure to visible light was investigated using MnFe 2 O 4 /Pani nanocomposite as a photocatalyst. The results exposed the faster degradation of MG dye was accomplished by MnFe 2 O 4 /Pani nanocomposite than MnFe 2 O 4 nanoparticles. The energy storage performance of the MnFe 2 O 4 /Pani nanocomposite was analyzed through cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy analyses. The results exposed that the MnFe 2 O 4 /Pani electrode achieved a capacitance of 287.1 F/g than the MnFe 2 O 4 electrode (94.55 F/g). Further, the respectable capacitance of 96.92% was achieved even after 3000 repetitive cycles stability. Based on the outcomes, the MnFe 2 O 4 /Pani nanocomposite can be suggested as a promising material for both photocatalytic and supercapacitor applications. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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