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[Display omitted] • Facile synthesis of anode material with organized structure. • Binary composite demonstrates better performance than its unitary counterpart. • In-situ XRD together with in-depth characterization reveals sodium ion storage. • DFT calculation verifies the sodium migration barrier. Sodium-ion batteries offer significant advantages in terms of low-temperature performance and safety. In this study, we present a straightforward synthetic approach to produce bimetallic selenide NiCoSe 2 nanoparticles grown on a three-dimensional porous carbon framework for application as anode materials in sodium-ion batteries. This unique architecture enhances reaction kinetics and structural stability. The three-dimensional interconnected porous carbon network establishes a continuous pathway of electronic conductive, while increasing specific surface area and mitigating volume expansion. Consequently, these features expedite ion transfer and enhance electrolyte interaction. Notably, compared to CoSe, NiCoSe 2 exhibits reduced ion transport distances and lower sodium diffusion barriers. Leveraging these attributes, NiCoSe 2 /N, Se co-doped carbon composite materials (NiCoSe 2 /NSC) demonstrate a high specific capacity of 320.8 mAh/g, even after 1000 cycles at 5.0 A/g, with a capacity retention rate of 85.1%. The study further delves into the revelation of the reaction mechanism and ion transport pathway through in-situ X-ray diffraction (XRD) analysis and theoretical calculations. The development of these anode materials is poised to pave the way for advancements in sodium-ion battery technology. [ABSTRACT FROM AUTHOR]