1. A high‐field magnetic birefringence study of dilute phases of a nonionic surfactant in water
- Author
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C. Y. Zhang, J. D. Litster, and S. Sprunt
- Subjects
Birefringence ,Pulmonary surfactant ,Chemistry ,Electrical resistivity and conductivity ,Liquid crystal ,Phase (matter) ,Analytical chemistry ,General Physics and Astronomy ,Physical and Theoretical Chemistry ,Neutron scattering ,Anisotropy ,Magnetic field - Abstract
We have used high‐resolution magnetic birefringence to study very dilute mixtures of the nonionic surfactant pentaethylene glycol mono‐dodecyl‐ether (C12E5) in water at fields to H=18 T. The induced refractive index anisotropy Δn shows distinct H dependencies in the Lα‐lamellar and L3‐‘‘sponge’’ phases, and demonstrates that these are separated by a two‐phase coexistence region. In the L3 phase and for surfactant concentrations γ≂0.02 (the vicinity of the Lα phase terminus), we observe a sharp change in the magnitude and H dependence of Δn. A quantitative analysis shows this to be consistent with a crossover from a highly‐connected ‘‘symmetric sponge’’ to a droplet or ‘‘asymmetric sponge’’ structure as a function of γ, a result previously suggested by neutron scattering and electrical conductivity measurements [R. Strey, R. Schomacker, D. Roux, F. Nallet, and U. Olssen, J. Chem. Soc. Faraday Trans. II 86, 2253 (1990)]. Finally, for γ≳0.02 and at large H, we present evidence of a field‐induced transformati...
- Published
- 1995
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