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Rock fragments of the Cb-type asteroid Ryugu returned to Earth by the JAXA Hayabusa2 mission share mineralogical, chemical, and isotopic properties with the Ivuna-type (CI) carbonaceous chondrites. Similar to CI chondrites, these fragments underwent extensive aqueous alteration and consist predominantly of hydrous minerals likely formed in the presence of liquid water on the Ryugu parent asteroid. Here we present an in situ analytical survey performed by secondary ion mass spectrometry from which we have estimated the D/H ratio of Ryugu's hydrous minerals, D/HRyugu, to be [165 ± 19] × 10⁻⁶, which corresponds to δDRyugu = +59 ± 121‰ (2σ). The hydrous mineral D/HRyugu's values for the two sampling sites on Ryugu are similar; they are also similar to the estimated D/H ratio of hydrous minerals in the CI chondrites Orgueil and Alais. This result reinforces a link between Ryugu and CI chondrites and an inference that Ryugu's samples, which avoided terrestrial contamination, are our best proxy to estimate the composition of water at the origin of hydrous minerals in CI-like material. Based on this data and recent literature studies, the contribution of CI chondrites to the hydrogen of Earth's surficial reservoirs is evaluated to be ∼3%. We conclude that the water responsible for the alteration of Ryugu's rocks was derived from water ice precursors inherited from the interstellar medium; the ice partially re-equilibrated its hydrogen with the nebular H₂ before being accreted on the Ryugu's parent asteroid., The Astrophysical Journal Letters, 946 (2), ISSN:1967-2014, ISSN:2041-8213

Establishing the abundance of the extinct radionuclide 60Fe (half-life 2.62 Ma) in the early solar system is important for understanding the astrophysical context of solar system formation. While bulk measurements of early solar system phases show a low abundance consistent with galactic background, some in situ measurements by secondary ion mass spectrometry (SIMS) imply a higher abundance, which would require injection from a nearby supernova (SN). Here we present in situ nickel isotopic analyses by resonance ionization mass spectrometry (RIMS) in a chondrule from the primitive meteorite Semarkona (LL3.00). The same chondrule had been previously analyzed by SIMS. Despite improved precision compared to SIMS, the RIMS nickel isotopic data do not reveal any resolved excesses of 60Ni that could be unambiguously ascribed to in situ 60Fe decay. Linear regression of 60Ni/58Ni versus 56Fe/58Ni yields an initial 60Fe/56Fe ratio for this chondrule of (3.8 ± 6.9) × 10−8, which is consistent with both the low initial value found by bulk measurements and the low end of the range of initial ratios inferred from some in situ work. The same regression also gives a solar initial 60Ni/58Ni ratio, which shows that this sample was not disturbed by nickel mobilization, thus agreeing with a low initial 60Fe/56Fe ratio. These findings agree with a re-evaluation of previous SIMS measurements of the same sample. Supernova injection of 60Fe into the solar system or its parental cloud material is therefore not necessary to account for the measured solar system's initial amount of 60Fe.

Use of the extinct 182 Hf- 182 W chronometer to constrain the timing of planetary accretion and differentiation rests ontheassumptionthatthesolarnebulahadhomogeneoustungstenisotopiccomposition.Here,wereportdeficiencies of � 0.1 part in 10,000 in the abundance of 184 Win group IVB iron meteorites relative to the silicate Earth. These are mostlikelyduetoincompletemixingattheplanetesimalscale(2Y4kmradiusbodies)oftheproductsof slow(s-)and rapid (r-) neutron-capture nucleosynthesis in the solar nebula. The correction that must be applied to the 182 Hf- 182 W model age of core formation in IVB irons due to the presence of these nuclear anomalies is � 0.5 Myr. Subject headingg minor planets, asteroids — nuclear reactions, nucleosynthesis, abundances — solar system: formation — stars: abundances

We present barium, carbon, and silicon isotopic compositions of 38 acid-cleaned presolar SiC grains from Murchison. Comparison with previous data shows that acid washing is highly effective in removing barium contamination. Strong depletions in $\delta$($^{138}$Ba/$^{136}$Ba) values are found, down to $-$400 permil, which can only be modeled with a flatter $^{13}$C profile within the $^{13}$C pocket than is normally used. The dependence of $\delta$($^{138}$Ba/$^{136}$Ba) predictions on the distribution of $^{13}$C within the pocket in AGB models allows us to probe the $^{13}$C profile within the $^{13}$C pocket and the pocket mass in asymptotic giant branch (AGB) stars. In addition, we provide constraints on the $^{22}$Ne$(\alpha,n)^{25}$Mg rate in the stellar temperature regime relevant to AGB stars, based on $\delta$($^{134}$Ba/$^{136}$Ba) values of mainstream grains. We found two nominally mainstream grains with strongly negative $\delta$($^{134}$Ba/$^{136}$Ba) values that cannot be explained by any of the current AGB model calculations. Instead, such negative values are consistent with the intermediate neutron capture process ($i$-process), which is activated by the Very Late Thermal Pulse (VLTP) during the post-AGB phase and characterized by a neutron density much higher than the $s$-process. These two grains may have condensed around post-AGB stars. Finally, we report abundances of two $p$-process isotopes, $^{130}$Ba and $^{132}$Ba, in single SiC grains. These isotopes are destroyed in the $s$-process in AGB stars. By comparing their abundances with respect to that of $^{135}$Ba, we conclude that there is no measurable decay of $^{135}$Cs ($t_{1/2}$= 2.3 Ma) to $^{135}$Ba in individual SiC grains, indicating condensation of barium, but not cesium into SiC grains before $^{135}$Cs decayed.

Progressive dissolution of the Murchison carbonaceous chondrite with acids of increasing strengths reveals large internal W isotope variations that reflect a heterogeneous distribution of s- and r-process W isotopes among the components of primitive chondrites. At least two distinct carriers of nucleosynthetic W isotope anomalies must be present, which were produced in different nucleosynthetic environments. The co-variation of 182W/184W and 183W/184W in the leachates follows a linear trend that is consistent with a mixing line between terrestrial W and a presumed s-process-enriched component. The composition of the s-enriched component agrees reasonably well with that predicted by the stellar model of s-process nucleosynthesis. The co-variation of 182W/184W and 183W/184W in the leachates provides a means for correcting the measured 182W/184W and 182W/183W of Ca-Al-rich inclusions (CAI) for nucleosynthetic anomalies using the isotopic variations in 183W/184W. This new correction procedure is different from that used previously, and results in a downward shift of the initial ?182W of CAI to ?3.51 ? 0.10 (where ?182W is the variation in 0.01% of the 182W/183W ratio relative to Earth's mantle). This revision leads to Hf-W model ages of core formation in iron meteorite parent bodies that are ~2?Myr younger than previously calculated. The revised Hf-W model ages are consistent with CAI being the oldest solids formed in the solar system, and indicate that core formation in some planetesimals occurred within ~2?Myr of the beginning of the solar system.

Among extinct radioactivities present in meteorites, 60Fe (t1/2 = 1.49 Myr) plays a key role as a high-resolution chronometer, a heat source in planetesimals, and a fingerprint of the astrophysical setting of solar system formation. A critical issue with 60Fe is that it could have been heterogeneously distributed in the protoplanetary disk, calling into question the efficiency of mixing in the solar nebula or the timing of 60Fe injection relative to planetesimal formation. If this were the case, one would expect meteorites that did not incorporate 60Fe (either because of late injection or incomplete mixing) to show 60Ni deficits (from lack of 60Fe decay) and collateral effects on other neutron-rich isotopes of Fe and Ni (coproduced with 60Fe in core-collapse supernovae and AGB-stars). Here, we show that measured iron meteorites and chondrites have Fe and Ni isotopic compositions identical to Earth. This demonstrates that 60Fe must have been injected into the protosolar nebula and mixed to less than 10 % heterogeneity before formation of planetary bodies.