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The occurrence of fluorotelomer alcohols (FTOHs) was investigated in 94 food-contact materials (FCMs). We detected 6:2 FTOH (<0.60--1110 ng/g), 8:2 FTOH (<0.40--8490 ng/g), and 10:2 FTOH (<0.02--9350 ng/g) in most FCM samples, and four longer-chain C14-20 FTOHs were, for the first time, identified in FCMs with relatively high concentrations (<0.02--8450 ng/g for 12:2 FTOH, <0.02--1640 ng/g for 14:2 FTOH, <0.02--372 ng/g for 16:2 FTOH, and <0.02--130 ng/g for 18:2 FTOH). There were three typical profiles of FTOHs that were dominated by 6:2 FTOH (95.6 ± 8.1% in 9 FCMs), 8:2 FTOH (50.9 ± 20.8% in 22 FCMs), and 10:2 FTOH (44.5 ± 20.9% in 30 FCMs), indicating the congener-specific usage of FTOHs for different commercial purposes. All nine detectable FCMs produced in the United States were dominated by 6:2 FTOH, which was significantly different from those produced in China. The median concentration of total FTOHs in eco-friendly paper tableware was 2990 ng/g, which was lower than in popcorn bags (18 200 ng/g) but much higher than other FCMs (<0.55--38.7 ng/g). FTOHs could migrate from paper bowls, with migration efficiencies of 0.004--0.24% into water, 0.004--0.24% into 10% ethanol, 0.009--2.79% into 30% ethanol, 0.06--13.0% into 50% ethanol (v/v) simulants, and 0.04--2.28% into oil. Migration efficiencies decreased with increasing carbon chain lengths of FTOHs. [ABSTRACT FROM AUTHOR]

States that the United States Environmental Protection Agency (EPA) has set effluent limits of dioxin based on the pulp processing technology in issuing rules to control the pulp and paper industry's combined air and water discharges. Details on the final rule; Comments from the EPA; Information on the amount pulp the United States pulp industry produces.

Presents a way to cut filter paper for microscale laboratory use developed by Calvin College in Michigan. Disadvantages to using cork borers for cutting filter paper for microscale use; Alternative filter paper punch.

Reports that kraft pulp mills would get eight years instead of three to implement emissions controls under proposed changes to the paper and pulp `cluster rule' in the United States. Amendment of the air component of the proposed cluster rule.

Solicits applications for the 1995 Perkin Elmer International LC Technical Paper Award. Eligibility; Prizes; Contact information.

Reports on projections by the Alliance for Environmental Innovation on the percentage of printing and writing paper used to make catalogs in the United States in 1999. Percentage to be used; Number of catalogs sent to citizens in 1998.

Industrial and agricultural off-gas streams are comprised of numerous volatile compounds, many of which have substantially different odorous properties. State-of-the-art waste-gas treatment includes the characterization of these molecules and is directed at, if possible, either the avoidance of such odorants during processing or the use of existing standardized air purification techniques like bioscrubbing or afterburning, which however, often show low efficiency under ecological and economical regards. Selective odor separation from the off-gas streams could ease many of these disadvantages but is not yet widely applicable. Thus, the aim of this paper is to identify possible model substances in selective odor separation research from 155 volatile molecules mainly originating from livestock facilities, fat refineries, and cocoa and coffee production by knowledge-based methods. All compounds are examined with regard to their structure and information-content using topological and information-theoretical indices. Resulting data are fitted in an observation matrix, and similarities between the substances are computed. Principal component analysis and k-means cluster analysis are conducted showing that clustering of indices data can depict odor information correlating well to molecular composition and molecular shape. Quantitative molecule describtion along with the application of such statistical means therefore provide a good classification tool of malodorant structure properties with no thermodynamic data needed. The approximate look-alike shape of odorous compounds within the clusters suggests a fair choice of possible model molecules. [ABSTRACT FROM AUTHOR]

Air pollution emissions regulation can affect the location, size, and technology choice of potential biofuel production facilities. Difficulty in obtaining air pollutant emission permits and the cost of air pollution control devices have been cited by some fuel producers as barriers to development. This paper expands on the Geospatial Bioenergy Systems Model (GBSM) to evaluate the effect of air pollution control costs on the availability, cost, and distribution of U.S. biofuel production by subjecting potential facility locations within U.S. Clean Air Act nonattainment areas, which exceed thresholds for healthy air quality, to additional costs. This paper compares three scenarios: one with air quality costs included, one without air quality costs, and one in which conversion facilities were prohibited in Clean Air Act nonattainment areas. While air quality regulation may substantially affect local decisions regarding siting or technology choices, their effect on the system as a whole is small. Most biofuel facilities are expected to be sited near to feedstock supplies, which are seldom in nonattainment areas. The average cost per unit of produced energy is less than 1% higher in the scenarios with air quality compliance costs than in scenarios without such costs. When facility construction is prohibited in nonattainment areas, the costs increase by slightly over 1%, due to increases in the distance feedstock is transported to facilities in attainment areas. [ABSTRACT FROM AUTHOR]

Gasoline direct injection (GDI) is a new engine technology intended to improve fuel economy and greenhouse gas emissions as required by recently enacted legislative and environmental regulations. The development of this technology must also ensure that these vehicles meet new LEV III and Tier 3 emissions standards as they phase in between 2017 and 2021. The aim of the present paper is to examine, at least for a small set, how the PM emissions from GDI vehicles change over their lifetime. The paper reports particle mass and number emissions of two GDI vehicles as a function of mileage up to 150K miles. These vehicles exhibit PM emissions that are near or below the upcoming 3 mg/mi FTP and 10 mg/mi US06 mass standards with little, if any, deterioration over 150K miles. Particle number emissions roughly follow the previously observed 2 × 1012 particles/mg correlation between solid particle number and PM mass. They remained between the interim and final EU stage 6 solid particle count standard for gasoline vehicles throughout the mileage accumulation study. These examples demonstrate feasibility to meet near-term 3 mg/mi and interim EU solid particle number standards, but continued development is needed to ensure that this continues as further fuel economy improvements are made. [ABSTRACT FROM AUTHOR]

Some 1,976 sites at closed military bases in the United States are contaminated with unexploded ordnance (UXO) left over from live-fire weapons training. These sites present risks to civilians who might come into contact with the UXO and cause it to explode. This paper presents the first systems analysis model for assessing the explosion risks of UXO at former military training ranges. We develop a stochastic model for estimating the probability of exposure to and explosion of UXO, before and after site cleanup. An application of the model to a 310-acre parcel at Fort Ord, California, shows that substantial risk can remain even after a site is declared clean. We estimate that risk to individual construction workers of encountering UXO that explodes would range from 4 × 10-4 to 5 × 10-2, depending on model assumptions, well above typical Occupational Safety and Health Administration (OSHA) and U.S. Environmental Protection Agency (EPA) target risk levels of 10-4 to 10-6. In contrast, a qualitative UXO risk assessment method, the Munitions and Explosives of Concern Hazard Assessment (MEC HA), developed by an interagency work group led by the EPA, indicates that the explosion risk at the case study site is low and "compatible with current and determined or reasonably anticipated future risk." We argue that a quantitative approach, like that illustrated in this paper, is necessary to provide a more complete picture of risks and the opportunities for risk reduction. [ABSTRACT FROM AUTHOR]

As part of the State Implementation Plan for attaining the National Ambient Air Quality Standard for ozone, the Texas Commission of Environmental Quality has created a Highly Reactive Volatile Organic Compounds (HRVOC) Emissions Cap and Trade Program for industrial point sources in the Houston/Galveston/Brazoria area. This program has a number of unique features, including its focus on a limited group of ozone precursors and its provisions for trading emissions based on atmospheric reactivity. This series of papers examines the potential air quality impacts of this new emission trading program through photochemical modeling of potential trading scenarios; this first paper in the series describes the air quality modeling methods used to assess potential trades, the potential for localized increases in ozone concentrations (ozone ‘hot spots’) due to HRVOC emission trading, and the use of reactivity scales in the trading. When HRVOC emissions are traded on a mass basis, the simulations indicate that trading of HRVOC allowances between facilities resulted in less than 0.15 ppb (<0.13%) and 0.06 ppb (<0.06%)increases in predicted maximum, area-wide 1-h averaged and 8-h averaged ozone concentrations, respectively. Maximum decreases in ozone concentrations associated with trading, as opposed to across-the-board reductions, were larger than the increases. All of these changes are small compared to the maximum changes in ozone concentrations due to the VOC emissions from these sources (up to 5–10 ppb for 8 h averages; up to 30 ppb for 1-h averages). When emissions of HRVOCs are traded for other, less reactive emissions, on a reactivity weighted basis, air quality simulations indicate that daily maximum ozone concentrations increased by less than 0.3%. Because these relatively small changes (<1%) are for unlikely trading scenarios designed to produce a maximum change in ozone concentrations (all emissions traded into localized regions), the simulations indicate that the implementation of the trading program, as currently configured and possibly expanded, is unlikely to cause localized increases in ozone concentrations (‘hot spots’). [ABSTRACT FROM AUTHOR]

The article presents a critical review on the significant developments in the inductively coupled plasma mass spectrometry (ICPMS) in chemical research from October 2003 to October 2005 in the U.S. Due to the publication of numerous papers that do not represent a significant advancement in ICPMS, the author recommends rejection of some manuscripts. It is the goal of the refereeing process to ensure the quality and significance of published papers in the field. In conclusion, the marginal importance of many published papers indicate a large variation in the reviewing process within a given journal. Proper selection of referees is also considered in this review.

The U.S. National Assessment of the Potential Consequences of Climate Variability and Change was a federally coordinated nationwide effort that involved thousands of experts and stakeholders. To draw lessons from this effort, the 10 authors of this paper, half of whom were not involved in the Assessment, developed and administered an extensive survey, prepared a series of working papers, and conducted an invitational workshop in Washington, DC, on April 29, 2004. Considering all these sources, the authors conclude that the Assessment was largely successful in implementing its basic design of distributed stakeholder involvement and in achieving its basic objectives. Future assessments could be significantly improved if greater attention were devoted to developing a collective understanding of objectives, preparing guidance materials and providing training for assessment participants, developing a budgeting mechanism which would allow greater freedom in allocating resources across various assessment activities, and creating an environment in which assessments were part of an ongoing process. [ABSTRACT FROM AUTHOR]

Methane emissions from municipal landfills represent 3% of the total United States greenhouse gas emissions that contribute to climate change. These methane emissions can be released to the air or collected and flared. This landfill gas also has the potential to be used to generate electricity. In 1994, the Environmental Protection Agency (EPA) created the Landfill Methane Outreach Program, with the objective of promoting the development of landfill-gas- to-energy projects around the country. There are currently 2,300 active landfills in the United States. Although there are already 382 operational projects, there are many more landfills with the potential to use the gas. EPA has identified at least 630 candidate landfills for energy projects, and many more have still not been identified. The objective of this paper is to evaluate total private and social benefits of landfill-gas-to-energy projects, taking into consideration not only the costs of installing and maintaining the necessary equipment and the revenues obtained from selling the electricity but also a valuation of the greenhouse gas emissions that would be prevented and the emissions of criteria pollutants created by the electricity generating equipment. It also evaluates the break-even government subsidies that would be required to make such projects economically viable from private and social perspectives in comparison to current subsidies. it was found that the private breakeven price of electricity for these projects is lower than $0.04/kWh. Moreover, the optimum social subsidy was found to be less than $0.0085/ kWh, which is about 40% lower than the currently available federal tax break of $0.015/kWh. The method developed for this paper can be applied to other renewable energy technologies, to show their relative social costs and benefits. [ABSTRACT FROM AUTHOR]

The need to use resources efficiently and reduce environmental impacts of industrial products and processes is becoming increasingly important in engineering design; therefore, green engineering principles are gaining prominence within engineering education. This paper describes a general framework for incorporating green engineering design principles into engineering curricula, with specific examples for chemical engineering. The framework for teaching green engineering discussed in this paper mirrors the 12 Principles of Green Engineering proposed byAnastas and Zimmerman (Environ. Sci. Technol 2003, 37, 94A-101A), especially in methods for estimating the hazardous nature of chemicals, strategies for pollution prevention, and approaches leading to efficient energy and material utilization. The key elements in green engineering education, which enlarge the "box" for engineering design, are environmental literacy, environmentally conscious design, and beyond-the-plant boundary considerations. [ABSTRACT FROM AUTHOR]

To the best of our knowledge, this study represents the first observation of multiday persistence of an indoor aerosol transformation linked to a kitchen degreaser containing monoethanol amine (MEA). MEA remaining on the cleaned surfaces and on a wiping paper towel in a trash can was able to transform ammonium sulfate and ammonium nitrate into (MEA)2SO4 and (MEA)NO3. This influence persisted for at least 60 h despite a high average ventilation rate. The influence was observed using both offline (filters, impactors, and ion chromatography analysis) and online (compact time-of-flight aerosol mass spectrometer) techniques. Substitution of ammonia in ammonium salts was observed not only in aerosol but also in particles deposited on a filter before the release of MEA. The similar influence of other amines is expected based on literature data. This influence represents a new pathway for MEA exposure of people in an indoor environment. The stabilizing effect on indoor nitrate also causes higher indoor exposure to fine nitrates. [ABSTRACT FROM AUTHOR]

This paper addresses water use impacts of agriculture, developing a spatially explicit approach tracing the location of water use and water scarcity related to feed production, transport, and livestock, tracking uncertainties and illustrating the approach with a case study on dairy production in the United States. This approach was developed as a step to bring spatially variable production and impacts into a process-based life cycle assessment (LCA) context. As water resources and demands are spatially variable, it is critical to take into account the location of activities to properly understand the impacts of water use, accounting for each of the main feeds for milk production. At the crop production level, the example of corn grain shows that 59% of water stress associated with corn grain production in the United States is located in Nebraska, a state with moderate water stress and moderate corn production (11%). At the level of milk production, four watersheds account for 78% of the national water stress impact, as these areas have high milk production and relatively high water stress; it is the production of local silage and hay crops that drives water consumption in these areas. By considering uncertainty in both inventory data and impact characterization factors, we demonstrate that spatial variability may be larger than uncertainty, and that not systematically accounting for the two can lead to artificially high uncertainty. Using a nonspatial approach in a spatially variable setting can result in a significant underestimation or overestimation of water impacts. The approach demonstrated here could be applied to other spatially variable processes. [ABSTRACT FROM AUTHOR]

The article discusses a report within the issue by researcher John Washington and colleagues of the U.S. Environmental Protection Agency (EPA) regarding the degradation time of perfluoropolymers. Fluorotelomer polymers are used in stain repellents and paper coatings and are a significant source of environmental perfluorooctanoic acid (PFOA). PFOA remains in the blood on individuals and the environment for years longer than previously thought. An overview of the study is presented.