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Your search keyword '"Li, YongXin"' showing total 1 results
Start Over Author "Li, YongXin" Topic carbene derivatives Topic ligands (chemistry) Publisher american chemical society
1 results on '"Li, YongXin"'

1. Synthesis and Reactivity of Cationic Iridium Aminocarbenes Derived from Terminal Alkynes and 2-Aminopyridines.

Author

Kumaran, Elumalai, How, Kai Tong Sonia, Ganguly, Rakesh, Li, Yongxin, and Leong, Weng Kee

Subjects
*REACTIVITY (Chemistry), *CATIONS, *ALKYNES, *AMINOPYRIDINES, *IRIDIUM compound synthesis, *CARBENE derivatives, *HYDROAMINATION, *LIGANDS (Chemistry), *SUBSTITUTION reactions
Abstract

Thereaction of a terminal alkyne (RCCH) and 2-aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2afforded the cationic aminocarbene derivativesCp*Ir(Cl)[ C(CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reactionpathway has been examined through computational studies. [ABSTRACT FROM AUTHOR]

Published
2013
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