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Human exposure to contaminated soils drives clean up criteria at many urban brownfields. Current risk assessment guidelines assume that humans ingest some fraction of soil smaller than 4 mm but have no estimates of what fraction of soil is - ingested by humans. Here, we evaluated soil adherence to human hands for 13 agricultural soils from Saskatchewan, Canada and 17 different soils from a brownfield located in lqaluit, Nunavut, Canada. In addition, we estimated average particle size adhering to human hands for residents of a northern urban setting. Further, we estimated how metal concentrations differed between the adhered and bulk (<4 mm) fraction of soil. The average particle size for adhered agricultural soils was 34 μm, adhered brownfiald soils was 105 μm, and particles adhered to human residents was 36 μm. Metals ware significantly enriched in these adhered fractions with an average enrichment [(adheredbulk)/bulk] in metal concentration of 184% (113% median) fur 24 different elements. Enrichment was greater for key toxicological elements of concern such as chromium (140%), copper (140%), nickel (130%), lead (110%), and zinc (130%) and was highest for silver (810%), mercury (630%), selenium (500%), and arsenic (420%). Enrichment were positively correlated with carbonate complexation constants (but not bulk solubility products) and suggests that the dominant mechanism controlling metal enrichment in these samples is a precipitation of carbonate surfaces that subsequently adsorb metals. Our results suggest that metals of toxicological concern are selectively enriched in the fraction of soil that humans incidentally ingest Investigators should likely process soil samples through a 45 μm sieve before estimating the risk associated with contaminated soils to humans. The chemical mechanisms resulting in metal enrichment likely differ between sites but at our site were linked to surface complexation with carbonates. [ABSTRACT FROM AUTHOR]