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1. Synthesis of 1,2-diamino-1,2-dideoxy-myo- inositol-derived ligands for the investigation of metal complex reactivity.

Author

Azev VN and D'Alarcao M

Subjects
Catalysis, Indicators and Reagents, Ligands, Magnetic Resonance Spectroscopy, Molecular Structure, Oxidation-Reduction, Inositol analogs & derivatives, Inositol chemical synthesis, Organometallic Compounds chemistry, Pyridines chemical synthesis
Abstract

A method for the synthesis of chiral 1,2-diamino-1,2-dideoxy-myo-inositol-based bis-pyridyl ligands 3a and 3b from the corresponding myo-inositol precursor is described. These highly functionalized inosamine-bis-pyridyl ligands are expected to provide a useful platform for exploring the relationship between chiral ligand structure and enantioselective olefin oxidation catalyzed by their metal complexes.

Published
2004
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