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8. Alanine scan of [L-[Dap.sup.2]]ramoplanin A2 aglycon: Assessment of the importance of each residue

9. Total synthesis of piericidin A1 and B1 and key analogues

10. Total synthesis of (-)- and ent-()-vindoline and related alkaloids

11. Intramolecular Diels - Alder/1,3-dipolar cycloaddition cascade f 1,3,4-oxadiazoles

12. Diastereoselective Diels-Alder reactions of N-sulfonyl-1-aza-1,3-butadienes with optically active enol ethers: An asymmetric variant of the 1-azadiene Diels-Alder reaction

13. Elucidation of fatty acid amide hydrolase inhibition by potent alpha-ketoheterocycle derivatives from Monte Carlo simulations

14. DNA alkylation properties of yatakemycin

15. Total synthesis of the Ramoplanin A2 and Ramoplanose Aglycon

18. Crystal structures of human GAR Tfase at low and high pH and with substrate beta-GAR

19. Total synthesis of anhydrolycorinone utilizing sequential intramolecular Diels-Alder reactions of a 1,3,4-oxadiazole

20. Mechanisms of in situ activation for DNA-targeting antitumor agents

21. Hairpin versus extended DNA binding of a substituted beta-alanine linked polyamide

22. Unexpected formation of an epoxide-derived multisubstrate adduct inhibitor on the active site of GAR transformylase

23. Parallel synthesis and evaluation of 132 (+)-1,2,9,9a-tetrahydrocyclopropa[c]benz[e]indol-4-one (CBI) analogues of CC-1065 and the duocarmycins defining the contribution of the DNA-binding domain

24. Metal cation complexation and activation of reversed CPyI analogues of CC-1065 and duocarmycin SA: partitioning the effects of binding and catalysis

26. Synthesis and evaluation of a series of C3-substituted CBI analogues of CC-1065 and the duocarmycins

27. Total synthesis of Fostriecin (CI-920)

28. Synthesis, chemical properties, and biological evaluation of CC-1065 and duocarmycin analogues incorporating the 5-methoxycarbonyl-1,2,9,9a-tetrahydrocyclopropa[c]benz[e]indol-4-one alkylation subunits

29. Total synthesis of thiocoraline and BE-22179 and assessment of their DNA binding and biological properties

30. Total synthesis of the rubrolone aglycon

31. Thermal atropisomerism of teicoplanin aglycon derivatives: Preparation of the P,P,P and M,P,P atropisomers of the teicoplanin aglycon via selective equilibration of the DE ring system

32. Development of a solution-phase synthesis of minor groove binding bis-intercalators based on triostin A suitable for combinatorial synthesis

33. Synthesis and evaluation of 1,2,8,8a-tetrahydrocyclopropa[c]pyrrolo[3,2-e]indol-4(5H)-one, the parent alkylation subunit of CC-1065 and the duocarmycins: impact of the alkylation subunit substituents and its implications for DNA alkylation catalysis

34. Selective metal cation activation of a DNA alkylating agent: synthesis and evaluation of methyl 1,2,9,9a-tetrahydrocyclopropa[c]pyrido[3,2-e]indol-4-one-7-carboxylate (CPyI)

35. Total synthesis of ningalin B utilizing a heterocyclic azadiene Diels-Alder reaction and discovery of a new class of potent multidrug resistant (MDR) reversal agents

36. Two comparisons of the performance of positional scanning and deletion synthesis for the identification of active constituents in mixture combinatorial libraries

37. New insights into inhibitor design from the crystal structure and NMR studies of Escherichia coli GAR transformylase in complex with beta-GAR and 10-formyl-5,8,10-trideazafolic acid

38. Total synthesis and comparative evaluation of luzopeptin A-C and quinoxapeptin A-C

39. Total synthesis of the vancomycin aglycon

40. Convergent solution-phase combinatorial synthesis with multiplication of diversity through rigid biaryl and diarylacetylene couplings

41. Are the duocarmycin and CC-1065 DNA alkylation reactions acid-catalyzed? Solvolysis pH-rate profiles suggest they are not

42. Synthesis and evaluation of duocarmycin and CC-1065 analogues containing modifications in the subunit linking amide

43. Total synthesis of HUN-7293

44. Binding-induced activation of DNA alkylation by duocarmycin SA: insights from the structure of an indole derivative-DNA adduct

45. Solution phase combinatorial synthesis of biaryl libraries employing heterogeneous conditions for catalysis and isolation with size exclusion chromatography for purification

46. Total synthesis of phomazarin

47. Total syntheses of ningalin A, lamellarin O, lukianol A, and permethyl storniamide A utilizing heterocyclic azadiene Diels-Alder reactions

48. Critical role of the linking amide in CC-1065 and the duocarmycins: implications on the source of DNA alkylation catalysis

49. Synthesis and evaluation of a carbocyclic analogue of the CC-1065 and duocarmycin alkylation subunits: role of the vinylogous amide and implications on DNA alkylation catalysis

50. A systematic evaluation of the bleomycin A2 L-threonine side chain: its role in preorganization of a compact conformation implicated in sequence-selective DNA cleavage