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Peracetic acid has quickly gained ground in water treatment over the last decade. Specifically, its disinfection efficacy toward a wide spectrum of microorganisms in wastewater is accompanied by the simplicity of its handling and use. Moreover, peracetic acid represents a promising option to achieve disinfection while reducing the concentration of typical chlorination byproducts in the final effluent. However, its chemical behavior is still amply debated. In this study, the reactivity of peracetic acid in the presence of halides, namely, chloride and bromide, was investigated in both synthetic waters and in a real contaminated water. While previous studies focused on the ability of this disinfectant to form halogenated byproducts in the presence of dissolved organic matter and halides, this work indicates that peracetic acid also contributes itself as a primary source in the formation of these potentially carcinogenic compounds. Specifically, this study suggests that 1.5 mM peracetic acid may form around 1-10 μg/L of bromoform when bromide is present. Bromoform formation reaches a maximum at near neutral pH, which is highly relevant for wastewater management.

In this work, contaminants of emerging concern were catalytically degraded in the homogeneous phase with the use of unconventional green reagents. Three reagents, namely, sulfite, metabisulfite, and persulfate, were tested and compared with conventional hydrogen peroxide in the degradation process activated by Fe-TAML. The latter is a biodegradable, homogeneous tetra-amido macrocyclic ligand catalyst containing iron(III). Metabisulfite showed the highest efficiency among the three tested reagents, and its reactivity was similar to that of H 2 O 2 . However, metabisulfite is a safer and cleaner reagent compared to H 2 O 2 . A comprehensive study of the activity of metabisulfite with Fe-TAML was carried out toward the oxidative degradation of eight contaminants of emerging concern. The catalytic process was tested at different pH values (7, 9, and 11). Metabisulfite showed the highest activity at pH 11, completely degrading some of the tested micropollutants, but in several cases, the system was active at pH 9 as well. In particular, metabisulfite showed the best efficiency toward phenolic compounds. A preliminary study on the reaction mechanism and the nature of the active species in the Fe-TAML/metabisulfite system was also conducted, highlighting that a high-valent iron-oxo species might be involved in the degradation pathways., Competing Interests: The authors declare no competing financial interest., (Copyright © 2019 American Chemical Society.)