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Access to high-performance and cost-effective catalyst materials is one of the crucial preconditions for the industrial application of electrochemical CO 2 reduction (ECR). In this work, a facile and simple strategy is proposed for the construction of a free-standing electrocatalyst via confining a superbase and hydrophobic ionic liquid (IL, [P 66614 ][triz]) into Ni foam pores, denoted as [P 66614 ][triz]@Ni foam. These ILs can modulate the surface of Ni foam and create a microenvironment with high CO 2 concentration around the electrode/electrolyte interface, which successfully suppresses the hydrogen evolution reaction (HER) of Ni foam. Consequently, the synthesized [P 66614 ][triz]@Ni foam sample can obtain a CO product with 63% Faradaic efficiency from the ECR procedure, while no detectable CO can be found on pristine Ni foam. Owing to the superbase IL, the valency of Ni species retains Ni(I)/Ni(0) during electrolysis. Furthermore, the strikingly high CO 2 capacity by [P 66614 ][Triz] (0.91 mol CO 2 per mole of IL) offers a high CO 2 local concentration in the reaction region. Theoretical calculations indicated that the neutral CO 2 molecule turned to be negatively charged with -0.546 e and changed into a bent geometry, thus rendering CO 2 activation and reduction in a low-energy pathway. This study provides a new method of electrode interface modification for the design of efficient ECR catalysts.