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Start Over Author "Hoan Nguyen Cong" Publisher american chemical society
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1. Synthesis and magnetic properties of new mono- and binuclear iron complexes with salicyloylhydrazono dithiolane ligand

Author

Bouslimani, Nouri, Clement, Nicolas, Rogez, Guillaume, Turek, Philippe, Bernard, Maxime, Dagorne, Samuel, Martel, David, Hoan Nguyen Cong, and Welter, Richard

Subjects
Iron compounds -- Chemical properties, Iron compounds -- Structure, Iron compounds -- Magnetic properties, Salicylates -- Research, Chlorine compounds -- Chemical properties, Chlorine compounds -- Structure, Chlorine compounds -- Magnetic properties, Chemistry
Abstract

The synthesis, structures and magnetic properties of some new [Fe.sup.III] and [Fe.sup.II] complexes are described, which has shown the rich coordination chemistry of the multidentate hydrazido salicyl derivative ligands bearing sulfur groups. The studies have shown an unexpected spontaneous reduction of the new [Fe.sup.III][(HL).sub.2]Cl,S complex to the new [Fe.sup.II][([H.sub.2]L).sub.2][Cl.sub.2] high-spin mononuclear complex.

Published
2008

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