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A hybrid UV photodetector incorporating a blended active layer of molybdenum disulfate (MoS2) nanoflakes and zinc oxide (ZnO) quantum dots (QDs) on the Au core-shelled AuPd hybrid NPs (HNPs), namely, the MoS2*ZnO/HNP configuration, is demonstrated for the first time. In the proposed configuration, the hot carriers generated by the strong localized surface plasmon resonance (LSPR) of Au-shelled AuPd HNPs can be effectively collected at the ZnO QD's conduction band. The blended MoS2 nanoflakes also successfully absorb the high-energy photons, offering additional photocarriers. The optimized device demonstrates an increased photocurrent (I ph) of 1.49 × 10-3 A at 10 V under 54.9 mW/mm2, which offers improved performance parameters of a photoresponsivity (R) of 2,525 mA/W, a detectivity (D) of 7.251 × 1011 jones, and an external quantum efficiency (EQE) of 813% at 0.34 mW/mm2. The result is one of the best ZnO-based photodetectors demonstrated so far. The enhanced photocurrent is due to the greater photocarrier injections by the blended active layer of MoS2 nanoflakes and ZnO QDs on the Au-shelled AuPd HNPs. The finite-difference time-domain (FDTD) simulation confirms the significantly increased maximum local e-field intensity and hotspots of the MoS2*ZnO/HNP blended active layer. [ABSTRACT FROM AUTHOR]

Total synthesis of ()-isatisine A is described based on the application of a silyl-directed Mukaiyama-type [3 2]-annulation for the preparation of a fully substituted furan core. The indole branch forming the quaternary carbon center at C2 was constructed by addition to an intermediate N-acyliminium ion derived from aminal 4. In addition, the fused tetracyclic framework including furan core was built up using modified Buchwald amidation conditions. [ABSTRACT FROM AUTHOR]

A convergent synthesis of brevisamide (1) is described based on the application of the crotyl silane-based [4 + 2]-annulation used for the preparation of the advanced oxygenated tetrahydropyran intermediate 2. The side chain bearing a conjugated (E,E)-diene was efficiently constructed under modified Negishi cross-coupling conditions. [ABSTRACT FROM AUTHOR]