1. Photoinduced Bimolecular Electron Transfer in Ionic Liquids: Cationic Electron Donors.
- Author
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Boning Wu, Min Liang, Zmich, Nicole, Hatcher, Jasmine, Lall-Ramnarine, Sharon I., Wishart, James F., Maroncelli, Mark, and Castner Jr., Edward W.
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PHOTOINDUCED electron transfer , *IONIC liquids , *CATIONS , *ELECTRON donors , *SOLVENTS - Abstract
Recently, we have reported a systematic study of photoinduced electron-transfer reactions in ionic liquid solvents using neutral and anionic electron donors and a series of cyano-substituted anthracene acceptors [Wu, B.; Maroncelli, M.; Castner, E. W., Jr.Photoinduced Bimolecular Electron Transfer in Ionic Liquids. J. Am. Chem. Soc.139, 2017, 14568]. Herein, we report complementary results for a cationic class of 1-alkyl-4-dimethylaminopyridinium electron donors. Reductive quenching of cyano-substituted anthracene fluorophores by these cationic quenchers is studied in solutions of acetonitrile and the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Varying the length of the alkyl chain permits tuning of the quencher diffusivities in solution. The observed quenching kinetics are interpreted using a diffusion-reaction analysis. Together with results from the prior study, these results show that the intrinsic electron-transfer rate constant does not depend on the quencher charge in this family of reactions. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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