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Start Over Author "Mo, Mingjie" Publisher american chemical society
2 results on '"Mo, Mingjie"'

2. Catalytic asymmetric assembly of C3-monosubstituted chiral carbazolones and concise formal synthesis of (-)-aspidofractinine: application of enantioselective Pd-catalyzed decarboxylative protonation of carbazolones.

Author

Zhao R, Sun Z, Mo M, Peng F, and Shao Z

Subjects
Carbazoles chemistry, Catalysis, Hydrogenation, Indole Alkaloids chemistry, Molecular Structure, Stereoisomerism, Carbazoles chemical synthesis, Indole Alkaloids chemical synthesis, Palladium chemistry
Abstract

The first method for the asymmetric synthesis of C3-monosubstituted chiral carbazolones, structural motifs common in medicinal chemistry, has been achieved using Pd-catalyzed decarboxylative protonation of carbazolones. This methodology has been applied to the first catalytic enantioselective formal synthesis of (-)-aspidofractinine with step economy and simplicity.

Published
2014
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