1. Fast and Selective Detection of Cr(III) in Environmental Water Samples Using Phosphovanadate Y(V 0.2 P 0.8 O 4 ):Eu 3+ Fluorescence Nanorods.
- Author
-
Zeng HH, Wu H, Peng D, Liu F, Shi WG, and Qiu JD
- Subjects
- Environmental Monitoring, Europium chemistry, Fluorescent Dyes chemistry, Hydrogen-Ion Concentration, Ions chemistry, Vanadates chemistry, Wastewater analysis, Chromium analysis, Nanotubes chemistry, Spectrometry, Fluorescence methods, Water Pollutants, Chemical analysis
- Abstract
Phosphovanadate Y(V
0.2 P0.8 O4 ):Eu3+ nanorods have been created via a simple hydrothermal method and used for the highly sensitive and selective fluorescence detection of Cr3+ over other common heavy metal ions within a 10 min period. It was found that the fluorescence intensity of Y(V0.2 P0.8 O4 ):Eu3+ linearly decreases with Cr3+ concentrations ranging from 1 × 10-9 to 1.2 × 10-6 M. The sensing mechanism for Cr3+ is ascribed to the aggregation of Y(V0.2 P0.8 O4 ):Eu3+ nanorods triggered by Cr3+ ions owing to the high affinity of phosphate groups to metal ions. The excellent chemical stability, photostability over a wide pH range of 3-12, and high salt-tolerance performance with ionic strength from 1× 10-3 to 12 M of Y(V0.2 P0.8 O4 ):Eu3+ allow these nanorods to successfully overcome the photobleaching and pH-dependent fluorescence property of traditional organic fluorescence probes. These characteristics ensure their applicability to environmental monitoring of Cr3+ . The sensitive determination of Cr3+ in different environmental water samples demonstrated the potential application of Y(V0.2 P0.8 O4 ):Eu3+ as a practical environmental probe. With the help of a UV lamp (254 nm), the visual Cr3+ values for dynamic monitoring in industrial wastewater further verified that this method can even exhibit on-site visible features in daytime and night easily. This allows for the direct monitoring of environmental Cr3+ .- Published
- 2018
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