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Your search keyword '"Skeens-Jones, Lisa M."' showing total 1 results
Start Over Author "Skeens-Jones, Lisa M." Publisher american chemical society
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1. High-valent oxo, methoxorhenium complexes: models for intermediates and transition states in proton-coupled multi-electron transfer reactions

Author

Ram, M.S., Skeens-Jones, Lisa M., Johnson, Christopher S., Zhang, Xiao Lian, Stern, Charlotte, Yoon, Dong I., Selmarten, Donald, and Hupp, Joseph T.

Subjects
Rhenium -- Research, Oxidation-reduction reaction -- Models, Coordination compounds -- Analysis, Chemistry
Abstract

The reaction of trans-dioxorhenium complex with methyl trifluoromethanesulfonate produces high-valent, highly stable oxo-, methoxorhenium complexes. These complexes are identical to analogous oxo, hydroxo complexes of trans-dioxorhenium(V)tetrapyridyl species, which is a model system for interfacial two-electron, two proton transfer reaction sequences. High pH stabilizes the rhenium(IV) state for several complexes with respect to redox disproportionation.

Published
1995

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