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Your search keyword '"Cinque, Gianfelice"' showing total 23 results
Start Over Author "Cinque, Gianfelice" Publisher american chemical society (acs)
23 results on '"Cinque, Gianfelice"'

1. Hyperspectral Mapping of Human Primary and Stem Cells at Cell–Matrix Interfaces

Author

De Santis, Emiliana, primary, Faruqui, Nilofar, additional, Russell, Craig T., additional, Noble, James E., additional, Kepiro, Ibolya E., additional, Hammond, Katharine, additional, Tsalenchuk, Maria, additional, Ryadnov, Eugeni M., additional, Wolna, Magda, additional, Frogley, Mark D., additional, Price, Christopher J., additional, Barbaric, Ivana, additional, Cinque, Gianfelice, additional, and Ryadnov, Maxim G., additional

Published
2024
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2. Adsorption of Sulfur Dioxide in Cu(II)-Carboxylate Framework Materials: The Role of Ligand Functionalization and Open Metal Sites

Author

Li, Weiyao, primary, Li, Jiangnan, additional, Duong, Thien D., additional, Sapchenko, Sergei A., additional, Han, Xue, additional, Humby, Jack D., additional, Whitehead, George F. S., additional, Victórica-Yrezábal, Iñigo J., additional, da Silva, Ivan, additional, Manuel, Pascal, additional, Frogley, Mark D., additional, Cinque, Gianfelice, additional, Schröder, Martin, additional, and Yang, Sihai, additional

Published
2022
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5. Elucidating the Drug Release from Metal–Organic Framework Nanocomposites via In Situ Synchrotron Microspectroscopy and Theoretical Modeling

Author

Souza, Barbara E., primary, Donà, Lorenzo, additional, Titov, Kirill, additional, Bruzzese, Paolo, additional, Zeng, Zhixin, additional, Zhang, Yang, additional, Babal, Arun S., additional, Möslein, Annika F., additional, Frogley, Mark D., additional, Wolna, Magda, additional, Cinque, Gianfelice, additional, Civalleri, Bartolomeo, additional, and Tan, Jin-Chong, additional

Published
2020
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7. Enhancement of CO2 Adsorption and Catalytic Properties by Fe-Doping of [Ga2(OH)2(L)] (H4L = Biphenyl-3,3′,5,5′-tetracarboxylic Acid), MFM-300(Ga2)

Author

Krap, Cristina, Newby, Ruth, Amarajothi, Dhakshinamoorthy, Garcia, Hermenegildo, Easun, Timothy, Cebula, Izabela, Savage, Mathew, Eyley, Jennifer, Gao, Shan, Blake, Alexander, Lewis, William, Beton, Peter, Warren, Mark, Allan, David, Frogley, Mark, Tang, Chiu, Cinque, Gianfelice, Dhakshinamoorthy, Amarajothi, García, Hermenegildo, Yang, Sihai, and Schröder, Martin

Subjects
STRUCTURAL-CHARACTERIZATION, SOLID-SOLUTIONS, FLUE-GAS, Heteroatom, 02 engineering and technology, Crystal structure, 010402 general chemistry, 01 natural sciences, Article, Catalysis, HYDROGEN ADSORPTION, Inorganic Chemistry, METAL-ORGANIC FRAMEWORKS, CARBON-DIOXIDE, chemistry.chemical_compound, QUIMICA ORGANICA, Adsorption, Styrene oxide, Organic chemistry, QD, CRYSTAL-STRUCTURE, Physical and Theoretical Chemistry, Isostructural, TP155, SITES, Chemistry, 021001 nanoscience & nanotechnology, 0104 chemical sciences, SULFUR-DIOXIDE, Crystallography, Metal-organic framework, Orthorhombic crystal system, POROUS HOST, 0210 nano-technology
Abstract

Metal-organic frameworks (MOFs) are usually synthesized using a single type of metal ion, and MOFs containing mixtures of different metal ions are of great interest and represent a methodology to enhance and tune materials properties. We report the synthesis of [Ga-2(OH)(2)(L)] (H4L = biphenyl-3,3',5,5'-tetracarboxylic acid), designated as MFM-300(Ga-2), (MFM = Manchester Framework Material replacing NOTT designation), by solvothermal reaction of Ga(NO3)(3) and H4L in a mixture of DMF, THF, and water containing HCl for 3 days. MFM-300(Ga-2) crystallizes in the tetragonal space group I4(1)22, a = b = 15.0174(7) angstrom and c = 11.9111(11) angstrom and is isostructural with the Al(III) analogue MFM-300(Al-2) with pores decorated with -OH groups bridging Ga(III) centers. The isostructural Fe-doped material [Ga1.87Fe0.13(OH)(2)(L)], MFM-300(Ga1.87Fe0.13), can be prepared under similar conditions to MFM-300(Ga-2) via reaction of a homogeneous mixture of Fe(NO3)(3) and Ga(NO3)(3) with biphenyl-3,3',5,5'-tetracarboxylic acid. An Fe(III)-based material [Fe3O1.5(OH)(HL)(L)(0.5)(H2O)(3.5)], MFM-310(Fe), was synthesized with Fe(NO3)(3) and the same ligand via hydrothermal methods. [MFM-310(Fe)] crystallizes in the orthorhombic space group Pmn2(1) with a = 10.560(4) angstrom, b = 19.451(8) angstrom, and c = 11.773(5) angstrom and incorporates mu(3)-oxo-centered trinuclear iron cluster nodes connected by ligands to give a 3D nonporous framework that has a different structure to the MFM-300 series. Thus, Fe-doping can be used to monitor the effects of the heteroatom center within a parent Ga(III) framework without the requirement of synthesizing the isostructural Fe(III) analogue [Fe-2(OH)(2)(L)], MFM-300(Fe-2), which we have thus far been unable to prepare. Fe-doping of MFM-300(Ga-2) affords positive effects on gas adsorption capacities, particularly for CO2 adsorption, whereby MFM-300(Ga1.87Fe0.13) shows a 49% enhancement of CO2 adsorption capacity in comparison to the homometallic parent material. We thus report herein the highest CO2 uptake (2.86 mmol g(-1) at 273 K at 1 bar) for a Ga-based MOF. The single-crystal X-ray structures of MFM-300(Ga-2)-solv, MFM-300(Ga-2), MFM-300(Ga-2)center dot 2.35CO(2), MFM-300(Ga1.87Fe0.13)-solv, MFM-300(Ga1.87Fe0.13), and MFM-300(Ga1.87Fe0.13)center dot 2.0CO(2) have been determined. Most notably, in situ single-crystal diffraction studies of gas-loaded materials have revealed that Fe-doping has a significant impact on the molecular details for CO2 binding in the pore, with the bridging M-OH hydroxyl groups being preferred binding sites for CO2 within these framework materials. In situ synchrotron IR spectroscopic measurements on CO2 binding with respect to the -OH groups in the pore are consistent with the above structural analyses. In addition, we found that, compared to MFM-300(Ga-2), Fe-doped MFM-300(Ga1.87Fe0.13) shows improved catalytic properties for the ring-opening reaction of styrene oxide, but similar activity for the room-temperature acetylation of benzaldehyde by methanol. The role of Fe-doping in these systems is discussed as a mechanism for enhancing porosity and the structural integrity of the parent material., We thank the Universities of Nottingham and Manchester for support. M.S. acknowledges receipt of an ERC Advanced Grant and EPSRC Programme Grant. We also thank EPSRC for funding of X-ray equipment. We acknowledge the use of instrumentation within the Nottingham Nanotechnology and Nanoscience Centre, and thank Dr. Christopher Parmenter for assistance. We thank Conacyt, Mexico, for funding to C.P.K. We are especially grateful to Diamond Light Source for access to Beamlines Ill (EE8943), 119 (MT7548, MT8448, MT8937), and B22 (SM11279).

Published
2016

8. Elucidating the Drug Release from Metal-Organic Framework Nanocomposites via in Situ Synchrotron Microspectroscopy and Theoretical Modelling

Author

Souza, Barbara, primary, Dona, Lorenzo, primary, Titov, Kirill, primary, Bruzzese, Paolo, primary, Zeng, Zhixin, primary, Zhang, Yang, primary, Babal, Arun, primary, Moslein, Annika, primary, Frogley, Mark, primary, Wolna, Magda, primary, Cinque, Gianfelice, primary, Civalleri, Bartolomeo, primary, and Tan, Jin-Chong, primary

Published
2019
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10. Chemotherapeutic Targets in Osteosarcoma: Insights from Synchrotron-MicroFTIR and Quasi-Elastic Neutron Scattering

Author

Marques, Maria Paula M., primary, Batista de Carvalho, Ana L. M., additional, Mamede, Adriana P., additional, Santos, Inês P., additional, García Sakai, Victoria, additional, Dopplapudi, Asha, additional, Cinque, Gianfelice, additional, Wolna, Magda, additional, Gardner, Peter, additional, and Batista de Carvalho, Luís A. E., additional

Published
2019
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12. OX-1 Metal–Organic Framework Nanosheets as Robust Hosts for Highly Active Catalytic Palladium Species

Author

Titov, Kirill, primary, Eremin, Dmitry B., additional, Kashin, Alexey S., additional, Boada, Roberto, additional, Souza, Barbara E., additional, Kelley, Chris S., additional, Frogley, Mark D., additional, Cinque, Gianfelice, additional, Gianolio, Diego, additional, Cibin, Giannantonio, additional, Rudić, Svemir, additional, Ananikov, Valentine P., additional, and Tan, Jin-Chong, additional

Published
2019
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14. Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal–Organic Frameworks

Author

Zhang, Xinran, primary, da Silva, Ivan, additional, Godfrey, Harry G. W., additional, Callear, Samantha K., additional, Sapchenko, Sergey A., additional, Cheng, Yongqiang, additional, Vitórica-Yrezábal, Inigo, additional, Frogley, Mark D., additional, Cinque, Gianfelice, additional, Tang, Chiu C., additional, Giacobbe, Carlotta, additional, Dejoie, Catherine, additional, Rudić, Svemir, additional, Ramirez-Cuesta, Anibal J., additional, Denecke, Melissa A., additional, Yang, Sihai, additional, and Schröder, Martin, additional

Published
2017
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15. Probing Dielectric Properties of Metal–Organic Frameworks: MIL-53(Al) as a Model System for Theoretical Predictions and Experimental Measurements via Synchrotron Far- and Mid-Infrared Spectroscopy

Author

Titov, Kirill, primary, Zeng, Zhixin, additional, Ryder, Matthew R., additional, Chaudhari, Abhijeet K., additional, Civalleri, Bartolomeo, additional, Kelley, Chris S., additional, Frogley, Mark D., additional, Cinque, Gianfelice, additional, and Tan, Jin-Chong, additional

Published
2017
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17. Synchrotron-Based Infrared Microanalysis of Biological Redox Processes under Electrochemical Control

Author

Ash, Philip A., primary, Reeve, Holly A., additional, Quinson, Jonathan, additional, Hidalgo, Ricardo, additional, Zhu, Tianze, additional, McPherson, Ian J., additional, Chung, Min-Wen, additional, Healy, Adam J., additional, Nayak, Simantini, additional, Lonsdale, Thomas H., additional, Wehbe, Katia, additional, Kelley, Chris S., additional, Frogley, Mark D., additional, Cinque, Gianfelice, additional, and Vincent, Kylie A., additional

Published
2016
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