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Nanoparticle-stabilized (Pickering) emulsions are widely used in applications such as cosmetics, drug delivery, membranes, and material synthesis. However, formulating Pickering nanoemulsions remains a significant challenge. Herein, we show that Pickering nanoemulsions can be obtained in a single step even at very low nanoparticle loadings (0.2 wt %) by condensing water vapor on a nanoparticle-infused subcooled oil that spreads on water. Droplet nuclei spontaneously submerge within the oil after nucleating at the oil-air interface, resulting in the suppression of droplet growth by diffusion, and subsequently coalesce to larger sizes until their growth is curtailed by nanoparticle adsorption. The average nanoemulsion size is governed by the competition between nanoparticle adsorption kinetics and droplet growth dynamics, which are in turn a function of nanoparticle size, concentration, and condensation time. Controlling such factors can lead to the formation of highly monodisperse nanoemulsions. Emulsion formation via condensation is a fast, scalable, energy-efficient process that can be adapted for a wide variety of emulsion-based applications in biology, chemistry, and materials science.

The surface properties of graphene quantum dots (GQDs) control their dispersion and location within the matrices of organic molecules and polymers, thereby determining various properties of the hybrid materials. Herein, we developed a facile, one-step method for achieving systematic control of the surface properties of highly fluorescent GQDs. The surfaces of the as-synthesized hydrophilic GQDs were modified precisely depending on the number of grafted hydrophobic hexylamine. The geometry of the modified GQDs was envisioned by conducting simulations using density functional theory. In stark contrast to the pristine GQDs, the surface-modified GQDs can effectively stabilize oil-in-water Pickering emulsions and submicron-sized colloidal particles in mini-emulsion polymerization. These versatile GQD surfactants were also employed in liquid-solid systems; we demonstrated their use for tailoring the dispersion of graphite in methanol. Finally, the particles produced by the GQD surfactants were fluorescent due to luminescence of the GQDs, which offers great potential for various applications, including fluorescent sensors and imaging.

We report the use of highly luminescent graphene quantum dots (GQDs) as efficient surfactants to produce Pickering emulsions and novel polymer particles. To generate the GQD surfactants, the surface properties of 10 nm sized, non-reduced GQDs (nGQDs), which have strong hydrophilicity, were synthesized and modified in a systematic manner by the thermal reduction of oxygen-containing groups at different treatment times. In stark contrast to the behavior of the nGQDs, thermally reduced GQDs (rGQDs) can produce highly stable Pickering emulsions of oil-in-water systems. To demonstrate the versatility of the rGQD surfactants, they were applied in a mini-emulsion polymerization system that requires nanosized surfactants to synthesize submicron-sized polystyrene particles. In addition, the use of rGQD surfactants can be extended to generating block copolymer particles with controlled nanostructures. Particularly, the polymer particles were highly luminescent, a characteristic produced by the highly fluorescent GQD surfactants, which has great potential for various applications, including bioimaging, drug delivery, and optoelectronic devices. To the best of our knowledge, this is the first report in which nanosized GQDs were used as surfactants.

Polymer-coated gold nanoparticles (Au NPs) with controlled size and surface chemistry were successfully synthesized and applied to tailor the structures and properties of polytriphenylamine (PTPA) and polystyrene (PS) blends. Two different polymer-coated Au NPs with sizes of 5.9 nm (Au NP-1) and 20.7 nm (Au NP-2) were designed to be thermally stable above 200 °C and neutral to both PS and PTPA phases. Hence, both Au NPs localize at the PS/PTPA interface and function as compatibilizers in the PS/PTPA blend. To show the compatibilizing effect of the particles, the morphological behaviors of PS/PTPA blends containing different particle volume fractions (ϕp) of Au NPs were observed using cross-sectional TEM, and for quantitative analysis, the size distribution of PTPA droplets in the PS matrix was obtained for each sample. The number-average droplet diameter (Dn) of the PTPA domain in the blend was dramatically reduced from 1.4 μm to 500 nm at a small ϕp of 1.0 vol % Au NP-1. The same trend of decreasing Dn w...

Pristine multiwalled carbon nanotubes (MWNTs) and zirconia-coated multiwalled carbon nanotubes (ZrO(2)/MWNTs) by isothermal hydrolysis and the traditional chemical precipitation method have been dispersed into polyvinylidene fluoride (PVDF) copolymer by solution mixing in N,N-dimethylformamide (DMF). The effect of ZrO(2)-coated MWNTs on morphological properties, electrical properties, and flame-retardant behavior has been studied in comparison with virgin PVDF and PVDF/MWNTs nanocomposites. Due to the improved dispersion of the coated nanotubes, the incorporation of 3 wt % of ZrO(2)-coated MWNTs leads to an increase of the thermal stability and dielectric properties and a decrease of the peak heat-release rate.