1. Femtosecond X-ray Spectroscopy Directly Quantifies Transient Excited-State Mixed Valency
- Author
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Chelsea Liekhus-Schmaltz, Zachary W. Fox, Amity Andersen, Kasper S. Kjaer, Roberto Alonso-Mori, Elisa Biasin, Julia Carlstad, Matthieu Chollet, James D. Gaynor, James M. Glownia, Kiryong Hong, Thomas Kroll, Jae Hyuk Lee, Benjamin I. Poulter, Marco Reinhard, Dimosthenis Sokaras, Yu Zhang, Gilles Doumy, Anne Marie March, Stephen H. Southworth, Shaul Mukamel, Amy A. Cordones, Robert W. Schoenlein, Niranjan Govind, and Munira Khalil
- Subjects
General Materials Science ,Physical and Theoretical Chemistry - Abstract
Quantifying charge delocalization associated with short-lived photoexcited states of molecular complexes in solution remains experimentally challenging, requiring local element specific femtosecond experimental probes of time-evolving electron transfer. In this study, we quantify the evolving valence hole charge distribution in the photoexcited charge transfer state of a prototypical mixed valence bimetallic iron-ruthenium complex, [(CN)
- Published
- 2022
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