267 results on '"Rauchfuss, Thomas B."'
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2. Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(Ex)(CN)2(CO)2]2– (E = S, Se, or Te)
3. Organometallic Fe2(μ-SH)2(CO)4(CN)2 Cluster Allows the Biosynthesis of the [FeFe]-Hydrogenase with Only the HydF Maturase
4. Challenges in the Synthesis of Active Site Mimics for [NiFe]-Hydrogenases
5. Homoleptic Rhodium Pyridine Complexes for Catalytic Hydrogen Oxidation
6. Crystal Structure of the [FeFe]-Hydrogenase Maturase HydE Bound to Complex-B
7. Vibrational Perturbation of the [FeFe] Hydrogenase H-Cluster Revealed by 13C2H-ADT Labeling
8. Computational and Experimental Investigations of the Fe2(μ-S2)/Fe2(μ-S)2 Equilibrium
9. Application of Hemilabile Ligands to “At-Metal Switching” Hydrogenation Catalysis
10. Radical SAM Enzyme HydE Generates Adenosylated Fe(I) Intermediates En Route to the [FeFe]-Hydrogenase Catalytic H-Cluster
11. Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates
12. Asymmetry in the Ligand Coordination Sphere of the [FeFe] Hydrogenase Active Site Is Reflected in the Magnetic Spin Interactions of the Aza-propanedithiolate Ligand
13. Iron Carbide–Sulfide Carbonyl Clusters
14. Redox and “Antioxidant” Properties of Fe2(μ-SH)2(CO)4(PPh3)2
15. Synthetic Designs and Structural Investigations of Biomimetic Ni–Fe Thiolates
16. Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation
17. Electron-Rich, Diiron Bis(monothiolato) Carbonyls: C–S Bond Homolysis in a Mixed Valence Diiron Dithiolate
18. Sterically Stabilized Terminal Hydride of a Diiron Dithiolate
19. Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory
20. Interplay between Terminal and Bridging Diiron Hydrides in Neutral and Oxidized States
21. Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct
22. Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy
23. Cobalt Phosphino-α-Iminopyridine-Catalyzed Hydrofunctionalization of Alkenes: Catalyst Development and Mechanistic Analysis
24. Imine-Centered Reactions in Imino-Phosphine Complexes of Iron Carbonyls
25. Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides
26. Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides
27. Insights into the Hydrolytic Polymerization of Trimethoxymethylsilane. Crystal Structure of (MeO)2MeSiONa
28. Synthesis of Diiron(I) Dithiolato Carbonyl Complexes
29. Preparation and Protonation of Fe2(pdt)(CNR)6, Electron-Rich Analogues of Fe2(pdt)(CO)6
30. Effect of Pyramidalization of the M2(SR)2 Center: The Case of (C5H5)2Ni2(SR)2
31. Models of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active Site
32. Spectroscopic Investigations of [FeFe] Hydrogenase Maturated with [57Fe2(adt)(CN)2(CO)4]2–
33. Diiron Azadithiolates as Models for the [FeFe]-Hydrogenase Active Site and Paradigm for the Role of the Second Coordination Sphere
34. N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and Complexation
35. Phosphine-Iminopyridines as Platforms for Catalytic Hydrofunctionalization of Alkenes
36. Cooperative Metal–Ligand Reactivity and Catalysis in Low-Spin Ferrous Alkoxides
37. Computational Investigation of [FeFe]-Hydrogenase Models: Characterization of Singly and Doubly Protonated Intermediates and Mechanistic Insights
38. Protonation of Nickel–Iron Hydrogenase Models Proceeds after Isomerization at Nickel
39. Multicopper Models for the Laccase Active Site: Effect of Nuclearity on Electrocatalytic Oxygen Reduction
40. Borane-Protected Cyanides as Surrogates of H-Bonded Cyanides in [FeFe]-Hydrogenase Active Site Models
41. Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site
42. New Reactions of Terminal Hydrides on a Diiron Dithiolate
43. NiI/RuII Model for the Ni–L State of the [NiFe]Hydrogenases: Synthesis, Spectroscopy, and Reactivity
44. Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates
45. Organo Ruthenium–Nickel Dithiolates with Redox-Responsive Nickel Sites
46. Hydrogen Activation by Biomimetic [NiFe]-Hydrogenase Model Containing Protected Cyanide Cofactors
47. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation
48. Isolation of a Mixed Valence Diiron Hydride: Evidence for a Spectator Hydride in Hydrogen Evolution Catalysis
49. Contrasting Protonation Behavior of Diphosphido vs Dithiolato Diiron(I) Carbonyl Complexes
50. Ligand Effects on the Overpotential for Dioxygen Reduction by Tris(2-pyridylmethyl)amine Derivatives
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