Massachusetts Institute of Technology. Center for Global Change Science, Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences, Rigby, Matthew, Ivy, Diane J., Prinn, Ronald G., Vollmer, Martin K., Miller, Benjamin R., Reimann, Stefan, Muhle, Jens, Krummel, P. B., O'Doherty, Simon, Kim, Jooil, Rhee, Tae Siek, Weiss, Ray F., Fraser, P. J., Simmonds, Peter G., Salameh, Peter K., Harth, C. M., Wang, Ray H. J., Steele, L. Paul, Young, Dickon, Lunder, Chris R., Hermansen, Ove, Arnold, Tim, Schmidbauer, Norbert, Kim, Kyung-Ryul, Greally, B. R., Hill, Matthias, Leist, Michael, Wenger, Angelina, Ivy, Diane J, Prinn, Ronald G, Massachusetts Institute of Technology. Center for Global Change Science, Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences, Rigby, Matthew, Ivy, Diane J., Prinn, Ronald G., Vollmer, Martin K., Miller, Benjamin R., Reimann, Stefan, Muhle, Jens, Krummel, P. B., O'Doherty, Simon, Kim, Jooil, Rhee, Tae Siek, Weiss, Ray F., Fraser, P. J., Simmonds, Peter G., Salameh, Peter K., Harth, C. M., Wang, Ray H. J., Steele, L. Paul, Young, Dickon, Lunder, Chris R., Hermansen, Ove, Arnold, Tim, Schmidbauer, Norbert, Kim, Kyung-Ryul, Greally, B. R., Hill, Matthias, Leist, Michael, Wenger, Angelina, Ivy, Diane J, and Prinn, Ronald G
We report on ground-based atmospheric measurements and emission estimates of the four anthropogenic hydrofluorocarbons (HFCs) HFC-365mfc (CH[subscript 3]CF[subscript 2]CH[subscript 2]CF[subscript 3], 1,1,1,3,3-pentafluorobutane), HFC-245fa (CHF[subscript 2]CH[subscript 2]CF[subscript 3], 1,1,1,3,3-pentafluoropropane), HFC-227ea (CF[subscript 3]CHFCF[subscript 3], 1,1,1,2,3,3,3-heptafluoropropane), and HFC-236fa (CF[subscript 3]CH[subscript 2]CF[subscript 3], 1,1,1,3,3,3-hexafluoropropane). In situ measurements are from the global monitoring sites of the Advanced Global Atmospheric Gases Experiment (AGAGE), the System for Observations of Halogenated Greenhouse Gases in Europe (SOGE), and Gosan (South Korea). We include the first halocarbon flask sample measurements from the Antarctic research stations King Sejong and Troll. We also present measurements of archived air samples from both hemispheres back to the 1970s. We use a two-dimensional atmospheric transport model to simulate global atmospheric abundances and to estimate global emissions. HFC-365mfc and HFC-245fa first appeared in the atmosphere only ∼1 decade ago; they have grown rapidly to globally averaged dry air mole fractions of 0.53 ppt (in parts per trillion, 10[superscript −12]) and 1.1 ppt, respectively, by the end of 2010. In contrast, HFC-227ea first appeared in the global atmosphere in the 1980s and has since grown to ∼0.58 ppt. We report the first measurements of HFC-236fa in the atmosphere. This long-lived compound was present in the atmosphere at only 0.074 ppt in 2010. All four substances exhibit yearly growth rates of >8% yr[superscript −1] at the end of 2010. We find rapidly increasing emissions for the foam-blowing compounds HFC-365mfc and HFC-245fa starting in ∼2002. After peaking in 2006 (HFC-365mfc: 3.2 kt yr[superscript −1], HFC-245fa: 6.5 kt yr[superscript −1]), emissions began to decline. Our results for these two compounds suggest that recent estimates from long-term projections (to the, United States. National Aeronautics and Space Administration (Grant NAG5‐12669), United States. National Aeronautics and Space Administration (Grant NNX07AE89G)