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Surface ocean iron (Fe) fertilization can affect the marine primary productivity (MPP), thereby impacting on CO2 exchanges at the atmosphere-ocean interface and eventually on climate. Mineral (aeolian or desert) dust is known to be a major atmospheric source for the surface ocean biogeochemical iron cycle, but the significance of volcanic ash is poorly constrained. We present the results of geochemical experiments aimed at determining the rapid release of Fe upon contact of pristine volcanic ash with seawater, mimicking their dry deposition into the surface ocean. Our data show that volcanic ash from both subduction zone and hot spot volcanoes (n = 44 samples) rapidly mobilized significant amounts of soluble Fe into seawater (35–340 nmol/g ash), with a suggested global mean of 200 ± 50 nmol Fe/g ash. These values are comparable to the range for desert dust in experiments at seawater pH (10–125 nmol Fe/g dust) presented in the literature (Guieu et al., 1996; Spokes et al., 1996). Combining our new Fe release data with the calculated ash flux from a selected major eruption into the ocean as a case study demonstrates that single volcanic eruptions have the potential to significantly increase the surface ocean Fe concentration within an ash fallout area. We also constrain the long-term (millennial-scale) airborne volcanic ash and mineral dust Fe flux into the Pacific Ocean by merging the Fe release data with geological flux estimates. These show that the input of volcanic ash into the Pacific Ocean (128–221 × 1015 g/ka) is within the same order of magnitude as the mineral dust input (39–519 × 1015 g/ka) (Mahowald et al., 2005). From the similarity in both Fe release and particle flux follows that the flux of soluble Fe related to the dry deposition of volcanic ash (3–75 × 109 mol/ka) is comparable to that of mineral dust (1–65 × 109 mol/ka). Our study therefore suggests that airborne volcanic ash is an important but hitherto underestimated atmospheric source for the Pacific surface ocean biogeochemical iron cycle.

[1] Sediment gravity cores collected on the Pacific slope and incoming plate offshore Central America reach up to 400 ka back in time and contain numerous ash layers from plinian eruptions at the Central American Volcanic Arc. The compositionally distinct widespread ash layers form a framework of marker horizons that allow us to stratigraphically correlate the sediment successions along and across the Middle America Trench. Moreover, ash layers correlated with 26 known eruptions on land provide absolute time lines through these successions. Having demonstrated the correlations in part 1, we here investigate implications for submarine sedimentary processes. Average accumulation rates of pelagic sediment packages constrained by bracketing tephras of known age range from ∼1–6 cm/ka on the incoming plate to 30–40 cm/ka on the continental slope. There are time intervals in which the apparent pelagic sedimentation rates significantly vary laterally both on the forearc and on the incoming plate where steady conditions are usually expected. A period of unsteadiness at 17–25 ka on the forearc coincides with a period of intense erosion on land probably triggered by tectonic processes. Unsteady conditions on the incoming plate are attributed to bend faulting across the outer rise triggering erosion and resedimentation. Extremely low apparent sedimentation rates at time intervals >50–80 ka suggest stronger tectonic activity than during younger times and indicate bend faulting is unsteady on a longer timescale. Submarine landslides are often associated with ash layers forming structurally weak zones used for detachment. Ash beds constrain ages of >60 ka, ∼19 ka, and

We collected 56 marine gravity cores from the Pacific seafloor offshore Central America which contain a total of 213 volcanic ash beds. Ash-layer correlations between cores and with their parental tephras on land use stratigraphic, lithologic, and compositional criteria. In particular, we make use of our newly built database of bulk-rock, mineral, and glass major and trace element compositions of plinian and similarly widespread tephras erupted since the Pleistocene along the Central American Volcanic Arc. We thus identify the distal ashes of 11 Nicaraguan, 8 El Salvadorian, 6 Guatemalan, and 1 Costa Rican eruptions. Relatively uniform pelagic sedimentation rates allow us to determine ages of 10 previously undated tephras by their relative position between ash layers of known age. Linking the marine and terrestrial records yields a tephrostratigraphic framework for the Central American volcanic arc from Costa Rica to Guatemala. This is a useful tool and prerequisite to understand the evolution of volcanism at a whole-arc scale.