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Sintering is one of the main causes of degradation of nanocatalysts. With a view to studying the process of sintering, and its relative likelihood across elements, we have used ab initio density functional theory to compute the pathways and energy barriers Ed for the diffusion of small clusters Ptn on MgO(001), n = 1–4. We compare with the corresponding results for Aun, Agn, and Pdn. In general, diffusion barriers, but also sintering energies, are highest for Pt, resulting in opposing trends from kinetics and thermodynamics. We find smooth and positive correlations between Ed and Eb, Eb and Ecoh, Ecoh and Tm, and thus, between Ed and Tm, where Eb is the binding energy of the cluster on MgO, and Ecoh and Tm are the cohesive energy and melting temperature, respectively, of the corresponding bulk metal. These trends are present for diffusion of the monomers, trimers, and tetramers, but not the dimers; this can be explained by the topography of the energy landscape separating the global minimum from the transition state. The temperature T0 at which metal clusters on a given support become mobile is given by α + βTm, where α and β are constants that depend on the support. We also present similar results for self-diffusion of monomers of the four metals on the (111) surfaces. Such scaling relations could be used to rapidly estimate diffusion barriers, and hence the growth and sintering behavior, of potential catalytic metal clusters. [ABSTRACT FROM AUTHOR]