1. Effect of chalcogens on Bi-Sb(Se-Te) based alloys made under inert gas pressure.
- Author
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Onarkulov, Maksad and Gaynazarova, Kizlarxon
- Subjects
- *
NOBLE gases , *THERMOELECTRIC materials , *ALLOYS , *CHALCOGENS , *ELECTRIC conductivity , *ELECTRIC currents - Abstract
Bi-Se-Sb-Te hard alloy-based elements are considered as one of the promising thermoelectric materials working in the temperature range of 200-600 K to solve current environmental and energy problems. There are technologies for obtaining hard alloys, ampoule method, Bridgeman method, Chokhral method, zone melting, melting with fluxes and melting under inert gas pressure. However, in the listed methods, it is observed that the introductions are not homogeneously distributed along the length of the alloy, and unnecessary introductions penetrate into the main component. Based on the above, a solid alloy based on Bi2Te3 and Bi2Se3 was obtained in the device for obtaining and alloying thermoelectric materials under inert gas pressure. Research of the electrophysical properties of the obtained materials, increasing the thermoelectric efficiency by introducing various inputs in excess of the stoichiometric composition, and the connection of the electrical conductivity and thermoelectric coefficients to the composition were studied. As a result, it was shown that a continuous system of solid alloys with high thermoelectric properties is formed in the Bi-Sb-Te-(Se) system. On the basis of the conducted analyses, the optimal conditions for the high efficiency and durability of thermoelectric materials, electrical conductivity and thermowell, and the passage of heat and electric currents were given. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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