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The authors reported organic phototransistors (PTs) with octadecyltrichlorosilane treated SiO2/Si substrate based on anthra[2,3-b]benzo[d]thiophene. The organic PTs show a high mobility of 0.4 cm2 V-1 s-1, a maximum photoresponsivity of about 1000 A/W, and photocurrent/dark-current ratio of around 800 under white light irradiation with 30 μW/cm2. The data are comparable with those of PTs based on amorphous silicon. Meanwhile, it is interesting to see that the devices show a high air-stable property and high photosensitivity via electric-field enhanced process. All these phenomena were attributed to the intrinsic optic-electronic property of the organic semiconductor and optic-electric field effect. [ABSTRACT FROM AUTHOR]

The aim of this study is to establish the structure-properties relationship of tetrathiafulvalene (TTF). After this study (1) TTF crystals with α and β phases were controllably obtained by the cast method with careful selection of the solvents, and (2) organic field-effect transistors (OFETs) of α and β phases both exhibited field-effect performance, and the performance of α phase was much better than that of β phase. The highest mobility of α phase reached 1.2 cm2 V-1 s-1, while β phase showed the maximum mobility only about 0.23 cm2 V-1 s-1, indicating the strong performance dependence of OFETs performance on the crystal phases. [ABSTRACT FROM AUTHOR]