Search

The <001>-oriented 0.7PMN–0.3PT and 0.67PMN–0.33PT crystals are characterized under uniaxial stress and electric field loading above the coercive field. Strain-electric-field and electric-displacement-electric-field hysteresis loops are measured at various compressive stresses showing a notable effect of stress on the electromechanical coupling. A moderate uniaxial stress can advance their electromechanical properties. Stress-strain curves are run at zero electric field, showing that depolarization for <001>-oriented 0.7PMN–0.3PT crystal begins at 7 MPa, while as little as 3 MPa for 0.67PMN–0.33PT crystal, placing a severe limitation in actuator applications. [ABSTRACT FROM AUTHOR]

KNbO3-based ferroelectrics have drawn much attention in recent years owing to their good piezoelectric performance among Pb-free piezoelectrics. However, little is known about the aging effect of these materials. In the present study, the authors systematically studied the aging effect of a Mn-doped (K0.99Li0.01)(Nb0.65Ta0.35)O3 ceramic with an aim to find an aging-induced recoverable electrostrain effect based on a reversible domain switching mechanism. They found that aging in the ferroelectric state made the otherwise normal hysteresis loop into a double loop, and more interestingly the aged sample demonstrated a large recoverable electrostrain of 0.125% at 4 kV/mm in an unpoled state. Such a behavior persisted up to 140 °C and showed good recoverability. The aging-induced double hysteresis and recoverable electrostrain suggest a reversible domain switching mechanism due to a symmetry-conforming short-range ordering of point defects. The striking similarity of the aging effect between acceptor-doped A+B5+O3 and acceptor-doped A2+B4+O3 systems indicates a common physical origin of aging. [ABSTRACT FROM AUTHOR]