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Titanium dioxide (TiO2) films have been prepared by DC reaction magnetron sputtering technique on different substrates (glass, SiO2, platinum electrode-Pt, Silicon-Si). X-ray diffraction (XRD) patterns showed that all TiO2 films were grown along the preferred orientation of (110) plane. Samples on Si and Pt substrates are almost monophasic rutile, however, samples on glass and SiO2 substrates accompanied by a weak anatase structure. Atomic force microscopy (AFM) images revealed uniform grain distribution except for films on Pt substrates. Photoluminescence (PL) spectra showed obvious intrinsic emission band, but films on glass was accompanied by a distinct defect luminescence region. Raman spectroscopy suggested that all samples moved to high wavenumbers and films on glass moved obviously. [ABSTRACT FROM AUTHOR]

The performance of dye-sensitized solar cells (DSSC) depends strongly on the electrolyte. In this paper, the electrolytes with various solvents and different potassium iodide (KI) & iodine (I2) concentration were prepared and their influence on the DSSC performance were investigated. The results revealed DSSC with electrolyte prepared by organic solvent show better performance than that of inorganic solvent. Meanwhile, the increasing of KI concentration from 0.1 to 0.6 mol/L can effectively improve the short-circuit current density (Jsc) from 0 2, correspondingly, the DSSC conversion efficiency (η) increased from 0.04% to 0.11%. On the other hand, the Jsc and η of DSSC increased firstly then decreased with the I2 concentration raised from 0.025 mol/L to 0.125 mol/L. It is worth to notice that the open-circuit voltage (Voc) of DSSC is almost unchanged with the concentration of KI and I2. In this paper, the best performance DSSC (Jsc=0.87 mA/cm2, Voc=0.57 mV, η=0.23%) can be obtained with electrolyte at a KI and I2 concentration of 0.6 mol/L and 0.075 mol/L respectively. Finally, the electrolytes used water and mixture of acetonitrile & ethylene glycol as solvents showed the latter presented better stability after setting at room temperature for 72 hours. [ABSTRACT FROM AUTHOR]