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The dynamic engineering of band structures for ultracold atoms in optical lattices represents an innovative approach to understanding and exploring the fundamental principles of topological matter. In particular, the folded Floquet spectrum determines the associated band topology via band inversion. We experimentally and theoretically study two-frequency phase modulation to asymmetrically hybridize the lowest two bands of a one-dimensional lattice. Using quasidegenerate perturbation theory in the extended Floquet space we derive an effective two-band model that quantitatively describes our setting. The energy gaps are experimentally probed via Landau-Zener transitions between Floquet-Bloch bands using an accelerated Bose-Einstein condensate. Separate and simultaneous control over the closing and reopening of these band gaps is demonstrated. We find good agreement between experiment and theory, establishing an analytic description for resonant Floquet-Bloch engineering that includes single- and multiphoton couplings, as well as interference effects between several commensurate drives., Physical Review Research, 4 (1), ISSN:2643-1564