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Your search keyword '"Komissarova, Ekaterina"' showing total 1 results
Start Over Author "Komissarova, Ekaterina" Publisher arkat usa inc.
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1. Synthesis of novel Y-shaped asymmetrical conjugated 2,4,6-trisubstituted pyrimidines and investigation of their optical and electrochemical properties.

Author

Komissarova, Ekaterina A., Sosnin, Evgenii, Shklyaeva, Elena V., Osorgina, Irina V., and Abashev, Georgii G.

Subjects
*PYRIMIDINE synthesis, *OXIDATION, *THIN films, *CARBAZOLE, *THIOPHENES, *FRONTIER orbitals, *ELECTROCHEMISTRY
Abstract

A set of novel Y-shaped asymmetrical pyrimidines has been prepared on the basis of 2-hydroxy-4,6- dimethylpyrimidine used as a starting compound. All of them are the chromophores of D-π-A-π-D' motif where A is a central pyrimidine core; D, D' are the thiophene-2-yl, thiophene-3-yl, 9-ethyl-9H-carbazol-3-yl or 9H-carbazole-9-yl- fragments and a π-bridge is a vinyl or styryl moiety. We have studied their optical, electrochemical and electrophysical characteristics, as well as their polymerizability with the help of electrochemical oxidation. [ABSTRACT FROM AUTHOR]

Published
2017
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