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This research, based on the 228 high-tech enterprises of Zhejiang province, mainly studies effect mechanism of innovation network and organizational learning on the innovation performance. On the basis of forefathers' research, this paper has established the "innovation network - organizational learning-innovation performance" model and the related hypotheses are verified by the empirical analysis. Research shows that the innovation network scale of enterprises, network centrality can directly promote enterprise innovation performance, knowledge acquisition and the use of knowledge can also directly promote enterprise innovation performance and innovation network can promote the innovation performance of enterprises through knowledge acquisition and the use of knowledge indirectly, which shows that organizational learning has a partially intermediary effect for innovation network and innovation performance.