Search

Your search keyword '"Jan Michalski"' showing total 1 results
Start Over Author "Jan Michalski" Publisher canadian science publishing
1 results on '"Jan Michalski"'

1. Cyclic organophosphorus compounds. III. Reactions of nitrosyl chloride with cyclic and open-chain hydrogen thiophosphites

Author

Jan Michalski and Andrzej Zwierzak

Subjects
chemistry.chemical_compound, Hydrogen, chemistry, Nucleophile, Chain (algebraic topology), Thiopyrophosphate, Organic Chemistry, chemistry.chemical_element, Nitrosyl chloride, General Chemistry, Medicinal chemistry, Catalysis
Abstract

2-Thiono-5,5-dimethyl-1,3,2-dioxaphosphorinan 1 treated with nitrosyl chloride yields a mixture of asymmetric 2 and symmetric 3 dithiopyrophosphates. Reinvestigation of the reaction of nitrosyl chloride with diethyl thiophosphite showed that, in addition to tetraethyl thiopyrophosphate, the corresponding dithiopyrophosphates are also formed. A mechanism is suggested for the reactions investigated, with nitrosyl chloride as an ambident nucleophile.

Published
1969
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results