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Start Over Author "Kayo Yamagishi" Publisher chemical society of japan
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1. Coordination Programming in the Design of Porous Coordination Polymers: Tuning of the Electronic Activity of Frameworks for Selective Nitrogen Monoxide Trapping.

Author

Wataru Kosaka, Kayo Yamagishi, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, and Hitoshi Miyasaka

Abstract

A change of building block from [Ru2II,II(p-FPhCO2)4] to [Ru2II,II(4-F-2-OMePhCO2)4] in a phenazine (phz)-bridged [Ru2II,II] chain compound led to a high selectivity toward nitrogen monoxide (NO) in the adsorption characteristics. High selectivity was observed despite the fact that electronically negative sites that enable close contact with NO molecules are not present in the pores, in contrast to [Ru2II,II(4-Cl-2-OMePhCO2)4(phz)], which also exhibited selective NO adsorption. [ABSTRACT FROM AUTHOR]

Published
2014
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