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The air-sea CO2 flux in the coastal ocean is a key component of the global carbon budget. However, due to the scarcity of data, the many sources and sinks of carbon and their complex interactions in these waters remain poorly understood. In 2021, the Tara schooner collected 14,000 km of CO2 fugacity (fCO2) measurements along the coast of South America, including in the Amazon River-Ocean continuum (https://doi.org/10.5281/zenodo.13790065 , Olivier et al., 2024a). The interactions between the Amazon River and its oceanic plume are complex, and under a combined influence of many processes such as tides and bathymetry. Downstream of the Amazon River plume, the fCO2 is low compared with that of the atmosphere, reaching a minimum of 42 μatm. In the river, fCO2 reaches up to 3000 μatm. South of the estuary, the waters of the North Brazil Current have a fCO2 exceeding 400 μatm. Along the Brazil Current, fCO2 is around 400 μatm and decreases, as does temperature, as the schooner sails away from the equator. Nevertheless, in all the data collected in this coastal environment, salinity varies greatly, and therefore describes best the variability of fCO2. Despite the strong variability and uncertainties in the data, comparison with discrete samples of other carbonate parameters shows that the mean differences (2 µatm) are within the range of uncertainties related to the chemical formula used for the comparison. This data set helps to fill the gap in our knowledge of the behavior of fCO2 in the under-sampled region of the Brazilian coast. [ABSTRACT FROM AUTHOR]

The temporal variation of the carbonate system, air–sea CO 2 fluxes, and pH is analyzed in the southern Indian Ocean, south of the polar front, based on in situ data obtained from 1985 to 2021 at a fixed station (50°40 ′ S–68°25 ′ E) and results from a neural network model that reconstructs the fugacity of CO 2 (fCO2) and fluxes at monthly scale. Anthropogenic CO 2 (C ant) is estimated in the water column and is detected down to the bottom (1600 m) in 1985, resulting in an aragonite saturation horizon at 600 m that migrated up to 400 m in 2021 due to the accumulation of C ant. At the subsurface, the trend of C ant is estimated at +0.53±0.01 µ mol kg -1 yr -1 with a detectable increase in the trend in recent years. At the surface during austral winter the oceanic fCO2 increased at a rate close to or slightly lower than in the atmosphere. To the contrary, in summer, we observed contrasting fCO2 and dissolved inorganic carbon (C T) trends depending on the decade and emphasizing the role of biological drivers on air–sea CO 2 fluxes and pH inter-annual variability. The regional air–sea CO 2 fluxes evolved from an annual source to the atmosphere of 0.8 molC m -2 yr -1 in 1985 to a sink of -0.5 molC m -2 yr -1 in 2020. Over 1985–2020, the annual pH trend in surface waters of -0.0165±0.0040 per decade was mainly controlled by the accumulation of anthropogenic CO 2 , but the summer pH trends were modulated by natural processes that reduced the acidification rate in the last decade. Using historical data from November 1962, we estimated the long-term trend for fCO2 , C T , and pH, confirming that the progressive acidification was driven by the atmospheric CO 2 increase. In 59 years this led to a diminution of 11 % for both aragonite and calcite saturation state. As atmospheric CO 2 is expected to increase in the future, the pH and carbonate saturation state will decrease at a faster rate than observed in recent years. A projection of future C T concentrations for a high emission scenario (SSP5-8.5) indicates that the surface pH in 2100 would decrease to 7.32 in winter. This is up to -0.86 lower than pre-industrial pH and -0.71 lower than pH observed in 2020. The aragonite undersaturation in surface waters would be reached as soon as 2050 (scenario SSP5-8.5) and 20 years later for a stabilization scenario (SSP2-4.5) with potential impacts on phytoplankton species and higher trophic levels in the rich ecosystems of the Kerguelen Islands area. [ABSTRACT FROM AUTHOR]

The temporal variation of the carbonate system, air-sea CO2 fluxes and pH is analyzed in the Southern Indian Ocean, south of the Polar Front, based on in-situ data obtained from 1985 to 2021 at a fixed station (50°40'S–68°25'E) and results from a neural network model that reconstructs the fugacity of CO2 (fCO2) and fluxes at monthly scale. Anthropogenic CO2 (Cant) was estimated in the water column and detected down to the bottom (1600 m) in 1985 resulting in an aragonite saturation horizon at 600 m that migrated up to 400 m in 2021 due to the accumulation of Cant. In subsurface, the trend of Cant is estimated at +0.53 (±0.01) µmol.kg-1.yr-1 with a detectable increase in recent years. At the surface during austral winter the oceanic fCO2 increased at a rate close or slightly lower than in the atmosphere. To the contrary, in summer, we observed contrasting fCO2 and dissolved inorganic carbon (CT) trends depending on the decade and emphasizing the role of biological drivers on air-sea CO2 fluxes and pH inter-annual variability. The region moved from an annual source of 0.8 molC.m-2.yr-1 in 1985 to a sink of -0.5 molC.m-2.yr-1 in 2020. In 1985–2020, the annual pH trend in surface of -0.0165 (± 0.0040).decade-1 was mainly controlled by anthropogenic CO2 but the trend was modulated by natural processes. Using historical data from November 1962 we estimated the long-term trend for fCO2, CT and pH confirming that the progressive acidification was driven by atmospheric CO2 increase. In 59 years this leads to a diminution of 11 % for both aragonite and calcite saturation state. As atmospheric CO2 will desperately continue rising in the future, the pH and carbonate saturation state will decrease at a faster rate than observed in recent years. A projection of future CT concentrations for a high emission scenario (SSP5-8.5) indicates that the surface pH in 2100 would decrease to 7.32 in winter. This is up to -0.86 lower than pre-industrial pH and -0.71 lower than pH observed in 2020. The aragonite under-saturation in surface waters would be reached as soon as 2050 (scenario SSP5-8.5) and 20 years later for a stabilization scenario (SSP2-4.5) with potential impacts on phytoplankton species and higher trophic levels in the rich ecosystems of the Kerguelen Island area. [ABSTRACT FROM AUTHOR]

The northwestern Tropical Atlantic Ocean is a turbulent region, filled with mesoscale eddies and regional currents. In this intense dynamical context, several water masses with thermohaline characteristics of different origins are advected, mixed, and stirred at the surface and at depth. The EUREC 4 A-OA/ATOMIC experiment that took place in January and February 2020 was dedicated to assessing the processes at play in this region, especially the interaction between the ocean and the atmosphere. For that reason, four oceanographic vessels and different autonomous platforms measured properties near the air–sea interface and acquired thousands of upper-ocean (up to 400–2000 m depth) profiles. However, each device had its own observing capability, varying from deep measurements acquired during vessel stations to shipboard underway near-surface observations and measurements from autonomous and uncrewed systems (such as Saildrones). These observations were undertaken with a specific sampling strategy guided by near-real-time satellite maps and adapted every half day, based on the process that was investigated. These processes were characterized by different spatiotemporal scales, from mesoscale eddies, with diameters exceeding 100 km, to submesoscale filaments of 1 km width. This article describes the datasets gathered from the different devices and how the data were calibrated and validated. In order to ensure an overall consistency, the platforms' datasets are cross-validated using a hierarchy of instruments defined by their own specificity and calibration procedures. This has enabled the quantification of the uncertainty in the measured parameters when different datasets are used together, e.g., 10.17882/92071. [ABSTRACT FROM AUTHOR]

The northwestern Tropical Atlantic Ocean is a turbulent region, filled with mesoscale eddies and large-scale currents. In this intense dynamical context, several water masses with thermohaline characteristics of different origins are advected, mixed, and stirred, at the surface and at depth. The EUREC4A-OA/ATOMIC experiment that took place in January and February 2020 was dedicated to assess the processes at play in this region, especially the interaction between the ocean and the atmosphere. For that, four oceanographic vessels and different autonomous platforms measured properties near the air-sea interface and acquired thousands of upper-ocean (400-2000 m) profiles. However, each device had its own observing capability, varying from deep measurements acquired during vessel stations to shipboard underway near-surface observations and measurements from autonomous and uncrewed systems (such as Saildrones). These observations were undertaken with a specific sampling strategy guided by near-real time satellite images and adapted every half day based on the process that was investigated. These processes were characterized by different spatio-temporal scales: from mesoscale eddies, with diameters exceeding 100 km, to submesoscale filaments of 1 km width. This article describes the data sets gathered from the different devices and how the data were calibrated and validated, in order to ensure an overall consistency, the platforms’ datasets are cross-validated using a hierarchy of instruments defined by their own specificity and calibration procedures. This has enabled the quantification of the uncertainty of the measured parameters when the different datasets are used together. [ABSTRACT FROM AUTHOR]

The key processes driving the air–sea CO2 fluxes in the western tropical Atlantic (WTA) in winter are poorly known. WTA is a highly dynamic oceanic region, expected to have a dominant role in the variability in CO2 air–sea fluxes. In early 2020 (February), this region was the site of a large in situ survey and studied in wider context through satellite measurements. The North Brazil Current (NBC) flows northward along the coast of South America, retroflects close to 8 ∘ N and pinches off the world's largest eddies, the NBC rings. The rings are formed to the north of the Amazon River mouth when freshwater discharge is still significant in winter (a time period of relatively low run-off). We show that in February 2020, the region (5–16 ∘ N, 50–59 ∘ W) is a CO2 sink from the atmosphere to the ocean (-1.7 TgC per month), a factor of 10 greater than previously estimated. The spatial distribution of CO2 fugacity is strongly influenced by eddies south of 12 ∘ N. During the campaign, a nutrient-rich freshwater plume from the Amazon River is entrained by a ring from the shelf up to 12 ∘ N leading to high phytoplankton concentration and significant carbon drawdown (∼20 % of the total sink). In trapping equatorial waters, NBC rings are a small source of CO2. The less variable North Atlantic subtropical water extends from 12 ∘ N northward and represents ∼60 % of the total sink due to the lower temperature associated with winter cooling and strong winds. Our results, in identifying the key processes influencing the air–sea CO2 flux in the WTA, highlight the role of eddy interactions with the Amazon River plume. It sheds light on how a lack of data impeded a correct assessment of the flux in the past, as well as on the necessity of taking into account features at meso- and small scales. [ABSTRACT FROM AUTHOR]

The characteristics of the CISE-LOCEAN seawater isotope dataset (δ18 O, δ2 H, referred to as δ D) are presented (10.17882/71186; Waterisotopes-CISE-LOCEAN, 2021). This dataset covers the time period from 1998 to 2021 and currently includes close to 8000 data entries, all with δ18 O, three-quarters of them also with δ D, associated with a date stamp, space stamp, and usually a salinity measurement. Until 2010, samples were analyzed by isotopic ratio mass spectrometry and since then mostly by cavity ring-down spectroscopy (CRDS). Instrumental uncertainty in this dataset is usually as low as 0.03 ‰ for δ18 O and 0.15 ‰ for δ D. An additional uncertainty is related to the isotopic composition of the in-house standards that are used to convert data to the Vienna Standard Mean Ocean Water (VSMOW) scale. Different comparisons suggest that since 2010 the latter have remained within at most 0.03 ‰ for δ18 O and 0.20 ‰ for δ D. Therefore, combining the two uncertainties suggests a standard deviation of at most 0.05 ‰ for δ18 O and 0.25 ‰ for δ D. For some samples, we find that there has been evaporation during collection and storage, requiring adjustment of the isotopic data produced by CRDS, based on d -excess (δ D - 8×δ18 O). This adjustment adds an uncertainty in the respective data of roughly 0.05 ‰ for δ18 O and 0.10 ‰ for δ D. This issue of conservation of samples is certainly a strong source of quality loss for parts of the database, and "small" effects may have remained undetected. The internal consistency of the database can be tested for subsets of the dataset when time series can be obtained (such as in the southern Indian Ocean or North Atlantic subpolar gyre). These comparisons suggest that the overall uncertainty of the spatially (for a cruise) or temporally (over a year) averaged data is less than 0.03 ‰ for δ18 O and 0.15 ‰ for δ D. However, 18 comparisons with duplicate seawater data analyzed in other laboratories or with other datasets in the intermediate and deep ocean suggest a larger scatter. When averaging the 18 comparisons done for δ18 O, we find a difference of 0.082 ‰ with a standard error of 0.016 ‰. Such an average difference is expected due to the adjustments applied at LOCEAN to saline water data produced either by CRDS or isotope ratio mass spectrometry (IRMS), but the scatter found suggests that care is needed when merging datasets from different laboratories. Examples of time series in the surface North Atlantic subpolar gyre illustrate the temporal changes in water isotope composition that can be detected with a carefully validated dataset. [ABSTRACT FROM AUTHOR]

The decadal changes in the fugacity of CO2 (fCO2) and pH in surface waters are investigated in the southern Indian Ocean (45–57 ∘ S) using repeated summer observations, including measurements of fCO2 , total alkalinity (AT) and total carbon (CT) collected over the period 1998–2019 in the frame of the French monitoring programme OISO (Océan Indien Service d'Observation). We used three datasets (underway fCO2 , underway AT – CT and station AT – CT) to evaluate the trends of fCO2 and pH and their drivers, including the accumulation of anthropogenic CO2 (Cant). The study region is separated into six domains based on the frontal system and biogeochemical characteristics: (i) high-nutrient low-chlorophyll (HNLC) waters in the polar front zone (PFZ) and (ii) north part and (iii) south part of HNLC waters south of the polar front (PF), as well as the highly productive zones in fertilised waters near (iv) Crozet Island and (v) north and (vi) south of Kerguelen Island. Almost everywhere, we obtained similar trends in surface fCO2 and pH using the fCO2 or AT – CT datasets. Over the period 1998–2019, we observed an increase in surface fCO2 and a decrease in pH ranging from + 1.0 to + 4.0 µ atm yr -1 and from - 0.0015 to - 0.0043 yr-1 , respectively. South of the PF, the fCO2 trend is close to the atmospheric CO2 rise (+ 2.0 µ atm yr -1), and the decrease in pH is in the range of the mean trend for the global ocean (around - 0.0020 yr-1); these trends are driven by the warming of surface waters (up to + 0.04 ∘ C yr -1) and the increase in CT mainly due to the accumulation of Cant (around + 0.6 µ mol kg -1 yr -1). In the PFZ, our data show slower fCO2 and pH trends (around + 1.3 µ atm yr -1 and - 0.0013 yr-1 , respectively) associated with an increase in AT (around + 0.4 µ mol kg -1 yr -1) that limited the impact of a more rapid accumulation of Cant north of the PF (up to + 1.1 µ mol kg -1 yr -1). In the fertilised waters near Crozet and Kerguelen islands, fCO2 increased and pH decreased faster than in the other domains, between + 2.2 and + 4.0 µ atm yr -1 and between - 0.0023 and - 0.0043 yr-1. The fastest trends of fCO2 and pH are found around Kerguelen Island north and south of the PF. These trends result from both a significant warming (up to + 0.07 ∘ C yr -1) and a rapid increase in CT (up to + 1.4 µ mol kg -1 yr -1) mainly explained by the uptake of Cant. Our data also show rapid changes in short periods and a relative stability of both fCO2 and pH in recent years at several locations both north and south of the PF, which leaves many open questions, notably the tipping point for the saturation state of carbonate minerals that remains highly uncertain. This highlights the need to maintain observations in the long-term in order to explore how the carbonate system will evolve in this region in the next decades. [ABSTRACT FROM AUTHOR]

The characteristics of the CISE-LOCEAN sea water isotope data set (δ18O, δ²H, later designed as δD) are presented. This data set covers the time period from 1998 to 2021 and currently includes close to 8000 data entries, all with δ18O, three quarters of them also with δD, associated with a time and space stamp and usually a salinity measurement. Until 2010, samples were analysed by isotopic ratio mass spectrometry, and since then mostly by cavity ring-down spectroscopy (CRDS). Instrumental uncertainty on individual data in this dataset is usually with a standard deviation as low as 0.03 / 0.15 ‰ for δ18O and δD. An additional uncertainty is related to uncertain isotopic composition of the in-house standards that are used to convert daily data into the VSMOW scale. Different comparisons suggest that since 2010 the latter have remained within at most 0.03 / 0.20 ‰ for δ18O and δD. Therefore, combining the two suggests a standard deviation of at most 0.05 / 0.25 ‰ for δ18O / δD. Finally, for some samples, we find that there has been evaporation during collection and storage, requiring adjustment of the isotopic data produced by CRDS, based on d-excess. This adds an uncertainty on the adjusted data of roughly 0.05 / 0.10 ‰ on δ18O and δD. This issue of conservation of samples is certainly a strong source of quality loss for parts of the database, and 'small' effects may have remained undetected. The internal consistency of the database can be tested for subsets of the dataset, when time series can be obtained (such as in the southern Indian Ocean or North Atlantic subpolar gyre). These comparisons suggest that the overall uncertainty of the spatially (for a cruise) or temporally (over a year) averaged data is on the order of or less than 0.03 / 0.15 ‰ for δ18O / δD. On the other hand, 17 comparisons with duplicate sea water data analysed in other laboratories or with other data sets in deep regions suggest a larger scatter. When averaging the 17 comparisons done for δ18O, we find a difference close to the adjustment applied at LOCEAN to convert salty water data from the activity to the concentration scale. Such a difference is expected, but the scatter found suggests that care is needed when merging datasets from different laboratories. Examples of time series in the surface North Atlantic subpolar gyre illustrate the temporal changes in water isotope composition that can be detected with a carefully validated dataset. [ABSTRACT FROM AUTHOR]

10 The decadal changes of the fugacity of CO2 (fCO2) and pH in surface waters are investigated in the Southern Indian Ocean (45°S-57°S) using repeated summer observations, including measurements of fCO2, total alkalinity (AT) and total carbon (CT) collected over the period 1998-2019 in the frame of the French monitoring program OISO. We used three datasets (underway fCO2, underway AT-CT and station AT-CT) to evaluate the trends of fCO2 and pH and their drivers, including the accumulation of anthropogenic CO2 (Cant). The study region is separated into three domains based on the frontal system 15 and biogeochemical characteristics: (i) High Nutrients Low Chlorophyll (HNLC) waters in the Polar Front Zone (PFZ), (ii) HNLC waters south of the Polar Front (PF) and (iii) the highly productive zones in fertilized waters near Crozet and Kerguelen Islands. Almost everywhere, we obtained similar trends in surface fCO2 and pH using the fCO2 or AT-CT datasets. Over the period 1998-2019, we observed an increase in surface fCO2 and a decrease in pH ranging from +1.0 to +4.0 µatm yr-1 and from -0.0015 to -0.0043 yr-1, respectively. South of the PF, the fCO2 trend is close to the atmospheric 20 CO2 rise (+2.0 µatm yr-1) and the decrease in pH is in the range of the mean trend for the global ocean (around -0.0020 yr- 1); these trends are driven by the warming of surface waters (up to +0.04°C yr-1) and the increase in CT, mainly due to the accumulation of Cant (around +0.6 µmol kg-1 yr-1). In the PFZ, our data show slower fCO2 and pH trends (around +1.3 µatm yr-1 and -0.0013 yr-1, respectively) associated with an increase in AT (around +0.4 µmol kg-1 yr-1) that limited the impact of a more rapid accumulation of Cant north of the PF (up to +1.1 µmol kg-1 yr-1). In the fertilized waters near Crozet and 25 Kerguelen Islands, fCO2 increased and pH decreased faster than in the other domains, between +2.2 and +4.0 µatm yr-1 and between -0.0023 yr-1 and -0.0043 yr-1. The fastest trends of fCO2 and pH are found around Kerguelen Island north and south of the PF. These trends result from both a significant warming (up to +0.07°C yr-1) and a rapid increase in CT (up to +1.4 µmol kg-1 yr-1), mainly explained by the uptake of Cant. Our data also show rapid changes on short periods and a relative stability of both fCO2 and pH in recent years at several locations both north and south of the PF, which leaves 30 many open questions, notably the tipping point for the saturation state of carbonate minerals that remains highly uncertain. This highlights the need to maintain observations on the long-term in order to explore how the carbonate system will evolve in this region in the next decades. [ABSTRACT FROM AUTHOR]

The North Brazil Current (NBC) flows northward across the Equator, passes the mouth of the Amazon River, and forms large oceanic eddies near 8° N. We investigate the processes driving the variability of air-sea CO2 fluxes at different scales in early 2020 in the region [50° W-59° W-5° N-16° N]. This region is a pathway between the equatorial and North Atlantic Ocean and was surveyed during the EUREC4A-OA/ATOMIC campaign. In-situ surface fugacity of CO2 (fCO2), salinity and temperature combined with maps of satellite salinity, chlorophyll-a and temperature highlight contrasting properties in the region. In February 2020, the area is a CO2 sink (-1.7 TgC.month-1), previously underestimated by a factor 10. The NBC rings transport saline and high fCO2 water indicative of their equatorial origins and are a small source of CO2 at regional scale. Their main impact on the variability of biogeochemical parameters is through the filaments they entrain into the open ocean. During the campaign, a nutrient-rich freshwater plume from the Amazon River is entrained from the shelf up to 12° N and caused a phytoplankton bloom leading to a significant carbon drawdown (~20 % of the total sink). On the other hand, saltier filaments of shelf water rich in detrital material act as strong local sources of CO2. Spatial distribution of fCO2 is therefore strongly influenced by ocean dynamics south of 12° N. The less variable North Atlantic subtropical water extends from Barbados northward. They represent ~60 % of the total sink due to their lower temperature associated with winter cooling and strong winds. [ABSTRACT FROM AUTHOR]

Variability of surface water masses of the Laptev and the East Siberian seas in August–September 2018 is studied using in situ and satellite data. In situ data were collected during the ARKTIKA-2018 expedition and then complemented with satellite-derived sea surface temperature (SST), salinity (SSS), sea surface height, wind speed, and sea ice concentration. The estimation of SSS fields is challenging in high-latitude regions, and the precision of soil moisture and ocean salinity (SMOS) SSS retrieval is improved by applying a threshold on SSS weekly error. For the first time in this region, the validity of DMI (Danish Meteorological Institute) SST and SMOS SSS products is thoroughly studied using ARKTIKA-2018 expedition continuous thermosalinograph measurements and conductivity–temperature–depth (CTD) casts. They are found to be adequate to describe large surface gradients in this region. Surface gradients and mixing of the river and the sea water in the ice-free and ice-covered areas are described with a special attention to the marginal ice zone at a synoptic scale. We suggest that the freshwater is pushed northward, close to the marginal ice zone (MIZ) and under the sea ice, which is confirmed by the oxygen isotope analysis. The SST-SSS diagram based on satellite estimates shows the possibility of investigating the surface water mass transformation at a synoptic scale and reveals the presence of river water on the shelf of the East Siberian Sea. The Ekman transport is calculated to better understand the pathway of surface water displacement on the shelf and beyond. [ABSTRACT FROM AUTHOR]

The North Atlantic is one of the major ocean sinks for natural and anthropogenic atmospheric CO2. Given the variability of the circulation, convective processes or warming–cooling recognized in the high latitudes in this region, a better understanding of the CO2 sink temporal variability and associated acidification needs a close inspection of seasonal, interannual to multidecadal observations. In this study, we investigate the evolution of CO2 uptake and ocean acidification in the North Atlantic Subpolar Gyre (50–64 ∘ N) using repeated observations collected over the last 3 decades in the framework of the long-term monitoring program SURATLANT (SURveillance de l'ATLANTique). Over the full period (1993–2017) pH decreases (-0.0017 yr -1) and fugacity of CO2 (fCO2) increases (+ 1.70 µ atm yr -1). The trend of fCO2 in surface water is slightly less than the atmospheric rate (+ 1.96 µ atm yr -1). This is mainly due to dissolved inorganic carbon (DIC) increase associated with the anthropogenic signal. However, over shorter periods (4–10 years) and depending on the season, we detect significant variability investigated in more detail in this study. Data obtained between 1993 and 1997 suggest a rapid increase in fCO2 in summer (up to +14 µ atm yr -1) that was driven by a significant warming and an increase in DIC for a short period. Similar fCO2 trends are observed between 2001 and 2007 during both summer and winter, but, without significant warming detected, these trends are mainly explained by an increase in DIC and a decrease in alkalinity. This also leads to a pH decrease but with contrasting trends depending on the region and season (between -0.006 and -0.013 yr -1). Conversely, data obtained during the last decade (2008–2017) in summer show a cooling of surface waters and an increase in alkalinity, leading to a strong decrease in surface fCO2 (between -4.4 and -2.3 µ atm yr -1 ; i.e., the ocean CO2 sink increases). Surprisingly, during summer, pH increases up to +0.0052 yr -1 in the southern subpolar gyre. Overall, our results show that, in addition to the accumulation of anthropogenic CO2 , the temporal changes in the uptake of CO2 and ocean acidification in the North Atlantic Subpolar Gyre present significant multiannual variability, not clearly directly associated with the North Atlantic Oscillation (NAO). With such variability it is uncertain to predict the near-future evolution of air–sea CO2 fluxes and pH in this region. Thus, it is highly recommended to maintain long-term observations to monitor these properties in the next decade. [ABSTRACT FROM AUTHOR]

Dissolved Fe (DFe) samples from the GEOVIDE voyage (GEOTRACES GA01, May–June 2014) in the North Atlantic Ocean were analyzed using a sea FAST -pico™ coupled to an Element XR sector field inductively coupled plasma mass spectrometer (SF-ICP-MS) and provided interesting insights into the Fe sources in this area. Overall, DFe concentrations ranged from 0.09±0.01 to 7.8±0.5 nmol L -1. Elevated DFe concentrations were observed above the Iberian, Greenland, and Newfoundland margins likely due to riverine inputs from the Tagus River, meteoric water inputs, and sedimentary inputs. Deep winter convection occurring the previous winter provided iron-to-nitrate ratios sufficient to sustain phytoplankton growth and lead to relatively elevated DFe concentrations within subsurface waters of the Irminger Sea. Increasing DFe concentrations along the flow path of the Labrador Sea Water were attributed to sedimentary inputs from the Newfoundland Margin. Bottom waters from the Irminger Sea displayed high DFe concentrations likely due to the dissolution of Fe-rich particles in the Denmark Strait Overflow Water and the Polar Intermediate Water. Finally, the nepheloid layers located in the different basins and at the Iberian Margin were found to act as either a source or a sink of DFe depending on the nature of particles, with organic particles likely releasing DFe and Mn particle scavenging DFe. [ABSTRACT FROM AUTHOR]

We present the Copernicus in situ ocean dataset of temperature and salinity (version 5.2). Ocean subsurface sampling varied widely from 1950 to 2017 as a result of changes in instrument technology and the development of in situ observational networks (in particular, tropical moorings for the Argo program). Thus, global ocean temperature data coverage on an annual basis grew from 10 % in 1950 (30 % for the North Atlantic basin) to 25 % in 2000 (60 % for the North Atlantic basin) and reached a plateau exceeding 80 % (95 % for the North Atlantic Ocean) after the deployment of the Argo program. The average depth reached by the profiles also increased from 1950 to 2017. The validation framework is presented, and an objective analysis-based method is developed to assess the quality of the dataset validation process. Objective analyses (OAs) of the ocean variability are calculated without taking into account the data quality flags (raw dataset OA), with the near-real-time quality flags (NRT dataset OA), and with the delayed-time-mode quality flags (CORA dataset OA). The comparison of the objective analysis variability shows that the near-real-time dataset managed to detect and to flag most of the large measurement errors, reducing the analysis error bar compared to the raw dataset error bar. It also shows that the ocean variability of the delayed-time-mode validated dataset is almost exempt from random-error-induced variability. [ABSTRACT FROM AUTHOR]

Understanding what controls the water vapor isotopic composition of the sub-cloud layer (SCL) over tropical oceans (δD0) is a first step towards understanding the water vapor isotopic composition everywhere in the troposphere. We propose an analytical model to predict δD0 motivated by the hypothesis that the altitude from which the free tropospheric air originates (zorig) is an important factor: when the air mixing into the SCL is lower in altitude, it is generally moister, and thus it depletes the SCL more efficiently. We extend previous simple box models of the SCL by prescribing the shape of δD vertical profiles as a function of humidity profiles and by accounting for rain evaporation and horizontal advection effects. The model relies on the assumption that δD profiles are steeper than mixing lines, and that the SCL is at steady state, restricting its applications to timescales longer than daily. In the model, δD0 is expressed as a function of zorig , humidity and temperature profiles, surface conditions, a parameter describing the steepness of the δD vertical gradient, and a few parameters describing rain evaporation and horizontal advection effects. We show that δD0 does not depend on the intensity of entrainment, in contrast to several previous studies that had hoped that δD0 measurements could help estimate this quantity. Based on an isotope-enabled general circulation model simulation, we show that δD0 variations are mainly controlled by mid-tropospheric depletion and rain evaporation in ascending regions and by sea surface temperature and zorig in subsiding regions. In turn, could δD0 measurements help estimate zorig and thus discriminate between different mixing processes? For such isotope-based estimates of zorig to be useful, we would need a precision of a few hundred meters in deep convective regions and smaller than 20 m in stratocumulus regions. To reach this target, we would need daily measurements of δD in the mid-troposphere and accurate measurements of δD0 (accuracy down to 0.1 ‰ in the case of stratocumulus clouds, which is currently difficult to obtain). We would also need information on the horizontal distribution of δD to account for horizontal advection effects, and full δD profiles to quantify the uncertainty associated with the assumed shape for δD profiles. Finally, rain evaporation is an issue in all regimes, even in stratocumulus clouds. Innovative techniques would need to be developed to quantify this effect from observations. [ABSTRACT FROM AUTHOR]

The North Atlantic is one of the major sinks for anthropogenic CO2. In this study, we investigate the evolution of CO2 uptake and ocean acidification in the North Atlantic Subpolar Gyre (50°N-64°N) using repeated observations collected over the last three decades in the framework of the long-term monitoring program SURATLANT (SURveillance de l'ATLANTique). Data obtained between 1993 and 1997 suggest an important reduction in the capacity of the ocean to absorb CO2 from the atmosphere during summer, due to a rapid increase in the fugacity of CO2 (fCO2) in surface waters (5 times faster than the increase in the atmosphere). This was associated with a rapid decrease in surface pH (of the order of -0.014/yr) and was mainly driven by a significant warming and increase in DIC. Similar trends are observed between 2001 and 2007 during both summer and winter with a mean decrease of pH between -0.006/yr and -0.013/yr. These rapid trends are mainly explained by a significant warming of surface waters, a decrease in alkalinity during summer and an increase in DIC during winter. On the contrary, data obtained during the last decade (2008-2017) show a stagnation of surface fCO2 (increasing the ocean sink for CO2) and pH. These recent trends are explained by the cooling of surface waters, a small decrease of total alkalinity and the near-stagnation of dissolved inorganic carbon. Overall our results show that the uptake of CO2 and ocean acidification in the North Atlantic Subpolar Gyre is substantially impacted by multi-decadal variability, in addition to the accumulation of anthropogenic CO2. As a consequence, the future evolution of air-sea CO2 fluxes, pH and the saturation state of surface waters with regards to aragonite and calcite remain highly uncertain in this region. [ABSTRACT FROM AUTHOR]

We present the Copernicus in-situ ocean dataset of temperature and salinity (version V5.2). The ocean subsurface sampling varied widely from 1950 to 2017, as a result of changes in the instrument technology and development of in-situ observational networks (in particular, tropical moorings, ARGO program). The global ocean temperature data coverage on an annual basis grows thus from 10% in 1950 (30% for the North Atlantic basin) to 25% in 2000 (60% for the North Atlantic basin) and reaches a plateau exceeding 80% (95% for the North Atlantic Ocean) after the deployment of the ARGO program. The average depth reached by the profiles also increases from 1950 to 2017. The validation framework is presented, and an objective analysis-based method is developed to assess the quality of the dataset validation process. Analyses of the ocean variability are calculated without taking into account the data quality flags (raw dataset OA), with the near real time quality flags (NRT dataset OA) and with the delayed time mode quality flags (CORA dataset OA). The comparison of the objective analysis variability shows that the near real time dataset managed to detect and to flag most of the large measurement errors, reducing the analysis error bar compared to the raw dataset error bar. It also shows that the ocean variability of the delayed time mode validated dataset is almost exempt from the random error induced variability. [ABSTRACT FROM AUTHOR]

We present a binned product of sea surface temperature, sea surface salinity, and sea surface density data in the North Atlantic subpolar gyre from 1993 to 2017 that resolves seasonal variability along specific ship routes (https://doi.org/10.6096/SSS-BIN-NASG). The characteristics of this product are described and validated through comparisons to other monthly products. Data presented in this work were collected in regions crossed by two predetermined ship transects, between Denmark and western Greenland (AX01) and between Iceland, Newfoundland, and the northeastern USA (AX02). The data were binned along a selected usable transect. The analysis and the strong correlation between successive seasons indicate that in large parts of the subpolar gyre, the binning approach is robust and resolves the seasonal timescales, in particular after 1997 and in regions away from the continental shelf. Prior to 2002, there was no winter sampling over theWest Greenland Shelf. Variability in sea surface salinity increases towards Newfoundland south of 54° N, as well as in the western Iceland Basin along 59° N. Variability in sea surface temperature presents less spatial structure with an increase westward and towards Newfoundland. The contribution of temperature variability to density dominates in the eastern part of the gyre, whereas the contribution of salinity variability dominates in the southwestern part along AX02. [ABSTRACT FROM AUTHOR]

Dissolved Fe (DFe) samples from the GEOVIDE voyage (GEOTRACES GA01, May-June 2014) in the North Atlantic Ocean were analysed using a SeaFAST-picoTM coupled to an Element XR HR-ICP-MS and provided interesting insights on the Fe sources in this area. Overall, DFe concentrations ranged from 0.09 ± 0.01 nmol L-1 to 7.8 ± 0.5 nmol L-1. Elevated DFe concentrations were observed above the Iberian, Greenland and Newfoundland Margins likely due to riverine inputs from the Tagus River, meteoric water inputs and sedimentary inputs. Air-sea interactions were suspected to be responsible for the increase in DFe concentrations within subsurface waters of the Irminger Sea due to deep convection occurring the previous winter, that provided iron-to-nitrate ratios sufficient to sustain phytoplankton growth. Increasing DFe concentrations along the flow path of the Labrador Sea Water were attributed to sedimentary inputs from the Newfoundland Margin. Bottom waters from the Irminger Sea displayed high DFe concentrations likely due to the dissolution of Fe-rich particles from the Denmark Strait Overflow Water and the Polar Intermediate Water. Finally, the nepheloid layers were found to act as either a source or a sink of DFe depending on the nature of particles. [ABSTRACT FROM AUTHOR]

We present a binned product of sea surface temperature, sea surface salinity and sea surface density data in the North Atlantic subpolar gyre for the 1993-2017 that resolves seasonal variability along specific ship routes (doi:10.6096/SSS-BIN-NASG). The characteristics of this product are described and validated through comparisons to other monthly products. Data presented in this work was collected in regions crossed by two predetermined ship transects, between Denmark and western Greenland (AX01) and between Iceland, Newfoundland, and the northeastern USA (AX02). The analysis and the strong correlation between successive seasons indicate that in large parts of the subpolar gyre, the binning approach is robust and resolves the seasonal time scales, in particular after 1997 and in regions away from the continental shelf. Prior to 2002, there was no winter sampling over the west Greenland shelf. Variability in sea surface salinity increases towards Newfoundland south of 54°N, as well as in the western Iceland Basin along 59°N. Variability in sea surface temperature presents less spatial structure with an increase westward and towards Newfoundland. The contribution of temperature variability to density dominates in the eastern part of the gyre, whereas the contribution of salinity variability dominates in the southwestern part along AX02. [ABSTRACT FROM AUTHOR]

In early 2020, an international team set out to investigate trade wind cumulus and their coupling to the large-scale circulation through the field campaign EUREC4A: ElUcidating the RolE of Clouds-Circulation Coupling in ClimAte. Focused on the western tropical Atlantic near Barbados, EUREC4A deployed a number of innovative observational strategies, including a large network of water isotopic measurements, to study the tropical shallow convective environment. The goal of the isotopic measurements was to elucidate processes that regulate the hydroclimate state -- for example, by identifying moisture sources, quantifying mixing between atmospheric layers, characterizing the microphysics that influence the formation and persistence of clouds and precipitation, and providing an extra constraint in the evaluation of numerical simulations. During EUREC4A, researchers deployed seven water vapor isotopic analyzers on two aircraft, on three ships, and at the Barbados Cloud Observatory (BCO). Precipitation was also collected for isotopic analysis at BCO and from aboard four ships. In addition, three ships collected seawater for isotopic analysis. All told, the in situ data span the period 5 January through 22 February 2020 and cover the approximate area 6 to 16° N and -50 to -60° W. Moreover, water vapor isotope ratios were measured from a few meters to nearly 8 km above sea level. This paper describes the full EUREC4A isotopic in situ data collection -- providing extensive information about sampling strategies and data uncertainties -- and also guides readers to complementary remotely sensed water vapor isotope ratios. DOIs for the multiple isotopic datasets are provided in Sect. 5 Data Availability. [ABSTRACT FROM AUTHOR]

During the 2017 SPURS-2 cruise, two multi-instrumented drifters drogued to the upper 60 cm of the surface were deployed for three hours. The drifters measured temperature and salinity in the top 50 cm, wave spectra and the noise of rain drops. During that time, the R/V Revelle did a short nearly-circular survey around them with a 1.8 km radius, measuring local weather and T-S stratification in the top 1 m (SSP). A SEA-POL radar also scanned the rain field except in the close vicinity of the ship. The radar captured a rain band moving to the west with small rainfall cells. The ship experienced short intense rain episodes totaling 1.3 cm accumulation, with mostly very low wind. The ship survey and the drifters showed large spatial heterogeneity, with maximum near-surface freshening of more than 8 psu measured at different times by the two drifters and at the ship. The freshening was also associated with large surface cooling. The vertical ocean structure also varied between these different low salinity events. In some cases, large surface freshening trapped to the upper 30 cm was observed despite no local rain. The salinity data suggest that some localized areas of less than 1 km horizontal scale likely experienced rain rates more than three times those measured on the ship. Furthermore, the spatial heterogeneity of salinity lasted for more than half an hour after the rain ended, probably associated with spreading and shallowing of the largest fresh pools, until the wind strengthened to the east of the cells. The structure of the rain cells and the likelihood of such large surface salinity heterogeneity is investigated. [ABSTRACT FROM AUTHOR]