1. Absorptivity of brown carbon in fresh and photo-chemically aged biomass-burning emissions
- Author
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Rawad Saleh, Allen L. Robinson, Neil M. Donahue, Christopher J. Hennigan, Ellis S. Robinson, Wayne Chuang, Gavin R. McMeeking, and Hugh Coe
- Subjects
Atmospheric Science ,geography ,geography.geographical_feature_category ,Environmental chamber ,Molar absorptivity ,Radiative forcing ,lcsh:QC1-999 ,Aerosol ,lcsh:Chemistry ,lcsh:QD1-999 ,Pocosin ,Environmental chemistry ,Hardwood ,Environmental science ,Brown carbon ,Biomass burning ,lcsh:Physics - Abstract
Experiments were conducted to investigate light absorption of organic aerosol (OA) in fresh and photo-chemically aged biomass-burning emissions. The experiments considered residential hardwood fuel (oak) and fuels commonly consumed in wild-land and prescribed fires in the United States (pocosin pine and gallberry). Photo-chemical aging was performed in an environmental chamber. We constrained the light-absorption properties of the OA using conservative limiting assumptions, and found that both primary organic aerosol (POA) in the fresh emissions and secondary organic aerosol (SOA) produced by photo-chemical aging absorb light to a significant extent, and are categorized as brown carbon. This work presents the first direct evidence that SOA produced in aged biomass-burning emissions is absorptive. For the investigated fuels, SOA is less absorptive than POA in the long visible, but exhibits steeper wavelength-dependence (larger Absorption Ångström Exponent) and is more absorptive in the short visible and near-UV. Light absorption by SOA in biomass-burning emissions might be an important contributor to the global radiative forcing budget.
- Published
- 2013
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