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The ethylene hydrogenation reaction was investigated in a kinetic turbo reactor and a one-sided single-pellet reactor. An empirical kinetic expression was fitted to experimental results taken from the turbo reactor, and the gas compositions at the catalyst centers were measured for three different pore structures by means of the single-pellet reactor. A bimodal pore model was developed and applied to the computation of the gas composition profiles inside the three pore structures. The calculated results were compared to the measurements. A distinct influence of the pore structures on the gas fluxes and concentration profiles inside the pores could be detected which demonstrates that the proper choice of the pellet pore structure is of importance for a high conversion. [ABSTRACT FROM AUTHOR]

Process intensification (PI) is a rapidly growing field of research and industrial development that has already created many innovations in chemical process industry. PI is directed toward substantially smaller, cleaner, more energy-efficient technology. Furthermore, PI aims at safer and sustainable technological developments. Its tools are reduction of the number of devices (integration of several functionalities in one apparatus), improving heat and mass transfer by advanced mixing technologies and shorter diffusion pathways, miniaturization, novel energy techniques, new separation approaches, integrated optimization and control strategies. This review discusses many of the recent developments in PI. Starting from fundamental definitions, microfluidic technology, mixing, modern distillation techniques, membrane separation, continuous chromatography, and application of gravitational, electric, and magnetic fields will be described. [ABSTRACT FROM AUTHOR]