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We present the first spectroscopic ALMA follow-up for a pilot sample of nine radio-selected near-IR-dark galaxies in the COSMOS field. These sources were initially selected as radio-detected sources (S3 GHz > 12.65 μJy) without an optical or near-IR (NIR) counterpart in the COSMOS2015 catalog (Ks ≳ 24.7 mag), and just three of them were subsequently detected in the deeper COSMOS2020. Several studies highlighted that this selection could provide a population of highly dust-obscured, massive, and star-bursting galaxies. With these new ALMA observations, we assess the spectroscopic redshifts of this pilot sample of sources and improve the quality of the physical properties estimated through SED-fitting. Moreover, we measure the quantity of molecular gas inside these galaxies and forecast their potential evolutionary path, finding that the radio-selected NIR-dark galaxies might likely represent a population of high-z progenitors of the massive and passive galaxies that were discovered at z ∼ 3. Finally, we present some initial constraints on the kinematics of the interstellar medium within the analyzed galaxies, reporting a high fraction (∼55%) of double-peaked lines that can be interpreted as the signature of a rotating structure in our targets or as the presence of major mergers in our sample. The results we present here show the scientific potential of (sub)mm observations for this elusive population of galaxies and highlight the potential contribution of these sources to the evolution of the massive and passive galaxies at high z. [ABSTRACT FROM AUTHOR]