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Biofilter technology has played a significant role over several decades in providing clean air through removal of Volatile Organic Compounds (VOCs) and odor causing chemicals such as hydrogen sulfide from industrial polluted airstreams. Biofilters where biological oxidation process takes place are designed and installed in numerous industrial facilities including chemical manufacturing, food processing, solid waste recycling and wastewater treatment plants to control emissions of VOCs, and odors in order to comply with the air emission regulations and to provide clean breathable air. Biofilter mathematical models under steady-state and transient conditions are essential in order to design, scale-up and predict biofilter performance under different operating conditions. Similarly, Artificial Intelligence (AI) through the use of Artificial Neural Network (ANN) modeling of biofiltration process is also becoming important. This research provides a detailed discussion and review of the recent (i.e., the last two decades) and important studies related to ANN, steady-state and transient biofilter models.

In this study, we addressed the prevalent issue of untreated greywater discharge into waterbodies in many developing countries, despite the associated public health risks. Our approach involved utilizing fibers extracted from plantain pseudo-stems to enhance the quality of greywater through simple biofiltration setups. Greywater sourced from the GETFund Hostel of the University of Energy and Natural Resources in Sunyani, Ghana, served as the focal point of our investigation. Through the application of this biofilter, we achieved notable reductions in two crucial parameters for assessing greywater quality: biochemical oxygen demand (BOD) and chemical oxygen demand (COD), averaging at 30.4 % and 28.67 %, respectively. Furthermore, we conducted comparative analyses between the efficacy of plantain pseudo-stem fibers and carbonized coconut shell adsorbent, both individually and in composite form as biosorbents. While certain combinations of biofilters led to slight increases in conductivity, pH, and total dissolved solids (TDS) in the treated greywater, these variations were anticipated and attributed to potential organic matter leaching during the biofiltration process. Employing Fourier-transform infrared (FT-IR) spectroscopy, we detected significant spectral changes indicative of successful organic matter removal from the greywater. Specifically, we observed an intensified phenolic hydroxyl (OH) peak at 3300 cm⁻¹, which shifted marginally to 3335 cm⁻¹ post-biofiltration. Additionally, the emergence of a carboxylic hydroxyl stretch at 2850 cm⁻¹ post-biofiltration provided strong evidence supporting the efficacy of our approach in mitigating organic contaminants in greywater.

Live Freshwater Mussels (FMs) have remarkable characteristics to support other species and the ecosystem. The objective of the study was to identify the planktonic composition; dye absorbance by living FMs; analyze the water quality indicators; and determine the heavy metals from FMs of different rivers in Bangladesh. In order to assess the planktonic composition, planktons were collected from the experimental ponds and then identified under the microscope. Methyl blue (MB) and methyl red (MR) dye absorbance were assessed using live FMs. After co-cultivating Silver barb (Barbonymus gonionotus) with FMs, water quality indicators (including pH, DO, hardness, total dissolved solids, ammonia, nitrite, and nitrate) were recorded. For determining heavy metals (Cu, Cr, Cd, Pb, Zn), mussels (Lamellidens marginalis) samples were collected from different rivers of Bangladesh. The findings of the study showed that the planktons were significantly (p

In degraded urban habitats, nature-based solutions aim to enhance ecosystem functioning and service provision. Bivalves are increasingly reintroduced to urban environments to enhance water quality through biofiltration, yet their long-term sustainability remains uncertain. Following the restoration of the disused South Docks in Liverpool in the 1980s, natural colonization of mussels rapidly improved dock-basin water quality and supported diverse taxa, including other filter feeders. While the initial colonization phase has been well documented, there has been limited published research since the mid-1990s, despite ongoing routine water quality monitoring. Here, we assessed the long-term persistence of mussel populations, their associated biodiversity, and physico-chemical parameters of the water in Queens and Albert Docks by comparing historical (1980s to 1990s) and contemporary data from follow-up surveys (2012,2022). Following an initial period of poor water quality (high contamination and turbidity, low oxygen), the natural colonization of mussels from Albert Dock in 1988 extended throughout the South Docks. By the mid-1990s, the environment of the South Docks and its mussel populations had stabilized. The dock walls were dominated by mussels which provided important complex secondary substrate for invertebrates and macroalgae. Surveys conducted in 2012 and 2022 confirmed the continued dominance of mussels and estimates of mussel biofiltration rates confirm that mussels are continuing to contribute to maintaining water quality. A decline in salinity was observed in both docks in 2022, with evidence of recovery. While these ecosystems appear relatively stable, careful management of the hydrological regime is crucial to ensuring the persistence of mussels and resilient ecosystem service provision through biofiltration., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Microplastic (MP) pollution has become a pressing global concern. Oysters are well-known filter feeders who ingest food by filtering microscopic particles suspended in the surrounding water. Along with organic matter, filter-feeding also causes accidental ingestion of MP by oysters. Hence, the aim of the current investigation is to understand the MP contamination in filter-feeding oysters. A total of 500 specimens of oyster Saccostrea cuccullata collected from the intertidal zone of five sampling locations on the Gujarat coast, India. Specimens underwent analysis following established protocols. Each specimen was found to exhibit MP contamination, showing an abundance of 2.72 ± 1.98 MPs/g. A negative relationship was found between shell length and MP abundance. Predominantly, fibers were documented across all study sites. Black, blue, and red-colored MPs with 1-2 mm sizes were most dominant. MP polymer composition was identified as polyethylene terephthalate and polypropylene. Findings provide baseline information on levels of MPs contamination, which can be used to monitor future effects of MP pollution., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Highly variable flow has to be expected in decentralized greywater treatment and can lead to intermittent operation of the treatment system. However, few studies have addressed the influence of variable flow on the treatment performance of a biological activated carbon filter (BAC). In this study, we investigated the influence of intermittent flow using small-scale BAC columns, which treat greywater as a second treatment step following a membrane bioreactor (MBR). Three operating strategies to respond to variable flow were evaluated. The activated carbon was characterized before and after the experiments in terms of biological activity and sorption capacity. The performance of the BAC filters was assessed based on total organic carbon (TOC) removal, TOC fractions and growth potential. No significant differences were observed between constant flow compared to on-off operation with intermittent flow over the range of tested influent concentrations. Peaks with high TOC during 24 h periods were attenuated by sorption and biological degradation. Adsorbed TOC was released after switching back to normal concentrations for influent concentrations more than 5 times higher than usually observed, the BAC functioned as a temporary sink. In line with these results, the high influent TOC values led to increased biological activity in the filter but did not influence the sorption capacity. The experiments showed that intermittent flow does not negatively impact the performance of a BAC and that there is no need for additional equalization tanks to buffer the variable flow, for example in household-scale greywater treatment.

Background: Sulphur-oxidizing microorganisms are widely used in the biofiltration of total reduced sulphur compounds (odorous and neurotoxic) produced by industries such as the cellulose and petrochemical industries, which include high-temperature process steps. Some hyperthermophilic microorganisms have the capability to oxidize these compounds at high temperatures (>60°C), and archaea of this group, for example, Sulfolobus metallicus, are commonly used in biofiltration technology. Results: In this study, a hyperthermophilic sulphur-oxidizing strain of archaea was isolated from a hot spring (Chillán, Chile) and designated as M1. It was identified as archaea of the genus Sulfolobus (99% homology with S. solfataricus 16S rDNA). Biofilms of this culture grown on polyethylene rings showed an elemental sulphur oxidation rate of 95.15 ± 15.39 mg S l-1 d-1, higher than the rate exhibited by the biofilm of the sulphur-oxidizing archaea S. metallicus (56.8 ± 10.91 mg l-1 d-1). Conclusions: The results suggest that the culture M1 is useful for the biofiltration of total reduced sulphur gases at high temperatures and for other biotechnological applications.

Both a theoretical and an empirical model were developed for predicting the formation of soluble microbial products (SMP) during drinking water biofiltration. Four pilot-scale biofilters with ceramsite as the medium were fed with different acetate loadings for the determination of SMP formation. Using numerically simulated and measured parameters, the theoretical model was developed according to the substrate and biomass balance. The results of this model matched the measured data better for higher SMP formation but did not fit well when SMP formation was lower. In order to better simulate the reality and overcome the difficulties of measuring the kinetic parameters, a simpler empirical model was also developed. In this model, SMP formation was expressed as a function of fed organic loadings and the depth of the medium, and a much better fit was obtained.

Odor emission seriously affects human and animal health, and the ecological environment. Nevertheless, a systematic summary regarding the control technology for odor emissions in livestock breeding is currently lacking. This paper summarizes odor control technology, highlighting its applicability, advantages, and limitations, which can be used to evaluate and identify the most appropriate methods in livestock production management. Odor control technologies are divided into four categories: dietary manipulation (low-crude protein diet and enzyme additives in feed), in-housing management (separation of urine from feces, adsorbents used as litter additive, and indoor environment/manure surface spraying agent), manure management (semi-permeable membrane-covered, reactor composting, slurry cover, and slurry acidification), and end-of-pipe measures for air treatment (wet scrubbing of the exhaust air from animal houses and biofiltration of the exhaust air from animal houses or composting). Findings of this paper provide a theoretical basis for the application of odor control technology in livestock farms., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Inc. All rights reserved.)

N,N-Dimethylformamide (DMF) is an organic solvent produced in large quantities worldwide. It is considered as a hazardous air pollutant and its emission should be controlled. However, only a limited number of studies have been performed on the removal of gaseous DMF by biological technologies. In this paper, we evaluate the removal of DMF under mesophilic and thermophilic conditions in a lab-scale biofilter for 472 days. The results show that, at ambient temperature, the biofilter achieved an average removal efficiency (RE) of 99.7 ± 0.3 % at Inlet Loads (ILs) up to 297 ± 52 g DFM m -3 h -1 (Empty Bed Residence Time (EBRTs) of 10.7 s). However, a decrease in EBRT (6.4 s) led to an unstable outlet concentration and, thus, to a drop in the biofilter performance (average RE: 90 ± 9 %). Moreover, an increase in temperature up to 65 °C led to a gradual decrease in RE (till 91 ± 7 %). Microbial analysis indicates that once the microorganisms encountered DMF, Rhizobiaceae dominated followed by Alcaligenaceae. Afterwards, a strong decrease in Rhizobiaceae was observed at every increase in temperature, and at 65 °C, the taxa were more heterogeneous. Overall, our experimental results indicate that biofiltration is a promising technique to remove DMF from waste gas streams., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Ozonation is an established solution for organic micropollutant (OMP) abatement in tertiary wastewater treatment. Biofiltration is the most common process for the biological post-treatment step, which is generally required to remove undesired oxidation products from the reaction of ozone with water matrix compounds. This study comparatively investigates the effect of filter media on the removal of organic contaminants and on biofilm properties for biologically activated carbon (BAC) and anthracite biofilters. Biofilms were analysed in two pilot-scale filters that have been operated for >50,000 bed volumes as post-treatment for ozonated wastewater treatment plant effluent. In parallel, the removal performance of bulk organics and OMP, including differentiation of adsorption and biotransformation through sodium azide inhibition, were carried out in bench-scale filter columns filled with material from the pilot filters. The use of BAC instead of anthracite resulted in an improved removal of organic bulk parameters, dissolved oxygen, and OMP. The OMP removal observed in the BAC filter but not in the anthracite filter was based on adsorption for most of the investigated compounds. For valsartan, however, biotransformation was found to be the dominant pathway, indicating that conditions for biotransformation of certain OMP are better on BAC than on anthracite. Adenosine triphosphate analyses in the media-attached biofilms of the pilot filters showed that biomass concentrations in the BAC filter were significantly higher than in the anthracite filter. The microbial communities (16S rRNA gene sequencing) appeared to be similar with respect to the types of organisms occurring on both filter materials. Alpha diversity also exhibited little variation between filter media. Beta diversity analysis, however, revealed that filter media and bed depth substantially influenced the biofilm composition. In practice, the impact of filter media on biofilm properties and biotransformation processes should be considered for the design of biofilters., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Biofilter (BF) has been regarded as a versatile gas treatment technology for removing volatile organic compounds (VOCs) from contaminated gas streams. In order for BF to be utilized in the industrial setting, it is essential to conduct research aimed at removing VOC mixtures under different inlet loading conditions, i.e. as a function of the gas flow rate and inlet VOC concentrations. The main aim of this study was to apply artificial neural networks (ANN) and determine the relationship between flow rate (FR), pressure drop (PD), inlet concentration (C), and removal efficiency (RE) in the BF treating gas-phase benzene and xylene mixtures. The ANN model was trained and tested to assess the removal efficiency of benzene (RE B ) and xylene (RE X ) under the influence of different FR, PD and C. The model's performance was assessed using a cross-validation method. The RE b varied from 20% to >60%, while the RE x varied from 10% to 70% during the different experimental phases of BF operation. The causal index (CI) technique was used to determine the sensitivity of the input parameters on the output variables. The ANN model with a topology of 4-4-2 performed the best in terms of predicting the RE profiles of both the pollutants. Furthermore, the effect was more pronounced for xylene because an increase in the benzene concentration reduced xylene removal (CI = -25.7170) more severely than benzene removal. An increase in the xylene concentration had a marginally positive effect on the benzene removal (CI = +0.1178)., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Inc. All rights reserved.)

A deoxidizing packing material (DPM) with an encapsulated deoxidizing agent (DA) was developed to construct the packed anodes of a trickle-bed microbial fuel cell (TB-MFC) for treating waste gas. The encapsulated DA can consume O 2 in waste gas and increase the voltage output and power density (PD) of the constructed TB-MFC. The DPM effectively enables the circulating water in TB-MFC for maintaining a low level of dissolved oxygen for 80 h. The results revealed that when the concentration of isopropanol (IPA) in waste gas was 0.74 g/m 3 , the TB-MFC (DPM with DA) exhibited an IPA removal efficiency (RE) of up to 99.7%. When DPM with DA was used as the packing material of the TB-MFC (486.6 mW/m 3 ), the PD was 2.54 times that obtained when using coke as the packing material (191.6 mW/m 3 ). The next-generation sequencing results demonstrated that because the oxygen content of the MFC anode chamber decreased over time in the TB-MFC, the richness of anaerobic electrogens (Pseudoxanthomonas, Flavobacterium, and Ferruginibacter) in the packing materials was increased. These electrogens mainly attached to the DPM, and IPA-degraders appeared in the circulating water of the TB-MFC. This enabled the TB-MFC to simultaneously achieve a high voltage output and IPA RE., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Continuously seeking the improvement of environmental protection, the limitation of exhaust emissions is of significance for the tire manufacturing industry. The aim of this study is to assess the potential of biofiltration for the treatment of such gaseous emissions. This work highlights that biofiltration is able to remove both hydrophilic and hydrophobic compounds within a single pilot unit of biofiltration. Due to Ethanol/Alkanes ratios (95/5 and 80/20), high performance levels were observed for low EBRT (16 and 12 s). After twenty days of stable running, the dynamic of stratification patterns could be explained as a result of species coexistence mechanisms. While its impact on performance has not been observed under stable operating conditions, the use of an adsorbent support such as granular activated carbon (GAC) could be relevant to promote system stability in the face of further perturbations, such as transient regimes, that are problematic in full-scale industrial applications., (Copyright © 2021 Elsevier B.V. All rights reserved.)

The combination of ozonation (O 3 ) and biofiltration processes has become practical and desirable in advanced water reclamation for water reuse applications. However, the role of microbial community and its characteristics (source, abundance, composition, viability, structure) on treatment performance has not received the same attention in water reclamation biofilters as in other applications, such as in drinking water biofilters. Microbial community characterization of biofilters used in water reuse applications will add evidence to better understand the potential microorganisms, consequent risks, and mechanisms that will populate drinking water sources and ultimately influence public health and the environment. This critical review provides insights into O 3 -biofiltration as a treatment barrier with a focus on development, structure, and composition of the microbial community characteristics involved in the process. The effect of microorganism seeding by the influent before and after the biofilter and ozone oxidation effects are explored to capture the microbial ecology interactions and environmental factors affecting the media ecosystem. The findings of reviewed studies concurred in identifying Proteobacteria as the most dominant phylum. However, Proteobacteria and other phyla relative abundance differ substantially depending upon environmental factors (e.g., pH, temperature, nutrients availability, among others) gradients. In general, we found significant gaps to relate and explain the biodegradation performance and metabolic processes within the biofilter, and hence deserve future attention. We highlighted and identified key challenges and future research ideas to assure O 3 -biofiltration reliability as a promising barrier in advanced water treatment applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

The packing material used in acidic biofilters (ABFs) has a significant impact on styrene removal. The bioaerosol emission was rarely considered when evaluating the packing materials in the ABFs. Four ABFs packed with ceramsite, compost, lava and polyurethane (PU) were developed and compared for their styrene removal and fungal bioaerosol emissions characteristics over 529 days. The removal efficiencies of styrene in the ABFs were higher under the condition of longer empty bed residence time (EBRT) and lower inlet concentration. The maximum styrene elimination capacities of the ABFs with ceramsite, compost, lava and PU were 74.57, 87.81, 67.13 and 101.88 g/m 3 h, respectively. A lower pressure drop and the highest fungi count were observed in the ABF packed with PU. The emissions concentrations of fungal bioaerosols at the humidity of 63.5% were lower than those at a humidity of 42.7% and it increased with the air velocity. Additionally, the concentrations of fungal bioaerosols emitted from the ABFs packed with PU were 2168 ± 145-3661 ± 257 CFU/m 3 , which was 33%-90% lower than those of the other three ABFs. The particle size distributions of the fungal bioaerosols emitted from the ABFs packed with PU and compost were mainly centered around large particles. Considering the removal of styrene and the fungal bioaerosols emissions, PU was the optimal packing material for ABF., (Copyright © 2020 Elsevier Inc. All rights reserved.)

Biofiltration is one of the main alternatives developed to improve wastewater quality and increase its recyclability. Support materials are extremely important when using this technology since they impact the cost of the treatment. In this work, we study the use of wood chips/peanut shell as support medium within biofilters incorporating microorganisms (BM), plants and microorganisms (BPM), earthworms and microorganisms (BEM) and all organisms (hybrid biofilters, HB). These typologies were evaluated to remove organic matter from synthetic domestic wastewater. For this purpose, twelve biofilters were operated in parallel under three different nominal hydraulic rates (0.5, 1 and 1.5 m 3  m -2  day -1 ). Previously, support materials were individually characterized and acute/chronic toxicity tests on plants (Eleocharis palustris (L.) Roem. & Schult.) and earthworms (Eisenia foetida Savigny) were driven. Results showed that both materials have good adsorbent properties, providing adequate environmental conditions for biofiltration. Moreover, non toxicological response was reported when a 25 v/v % peanut shell fraction was selected. With this fraction used in every biofilter studied, the average hydraulic conductivity was between 321 and 502 mm h -1 , reaching organic matter removal efficiencies close to 80% (measured as COD), and between 40 and 63% (measured as VS). Higher efficiencies, attributed to the longer contact times, and lower clogging were observed at lower hydraulic rates. The incorporation of earthworms and plants improved the solids removal and reduced clogging. The statistical analysis indicated that the results obtained for biofilters operating at 0.5 m 3  m -2  day -1 showed significant differences (p < 0.05) with respect to the other rates. Moreover, BEM were the ones that presented significant differences. As a conclusion, low-cost organic materials (wood chip/peanut shell mix) can be successfully used as support medium, since they provide adequate environmental conditions for plants and earthworms, improving the operation and maintaining contaminant (organic matter) removal within biofiltration typologies., Competing Interests: Declaration of competing interest We wish to confirm that there are no known conflicts of interest associated with this publication and there has been no significant financial support for this work that could have influenced its outcome. We confirm that the manuscript has been read and approved by all named authors and that there are no other persons who satisfied the criteria for authorship but are not listed. We further confirm that the order of authors listed in the manuscript has been approved by all of us. We confirm that we have given due consideration to the protection of intellectual property associated with this work and that there are no impediments to publication, including the timing of publication, with respect to intellectual property. In so doing we confirm that we have followed the regulations of our institutions concerning intellectual property. We further confirm that any aspect of the work covered in this manuscript that has involved either experimental animals or human patients has been conducted with the ethical approval of all relevant bodies and that such approvals are acknowledged within the manuscript., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Biological treatment of municipal wastewater for reuse in irrigation is highly required, especially with the current global financial and water shortage crises. Bioaugmentation is a simple and cost-effective technology which could be a useful tool in alleviating this challenge. Thus, this study aimed to enhance the biological treatment of municipal wastewater using a bioaugmented substance supplemented in a three-stages bio-filter consisting of a sedimentation step followed by gravel biofiltration and then sand biofiltration at a laboratory scale. Also, a toxicity assay, the antimicrobial effect of the bioaugmented substance against pathogenic microorganisms, and identification of the synergistic effect of the bacterial consortium involved in the bioaugmented substance were studied. The bioaugmented substance was nontoxic and had an antimicrobial effect against the tested potentially pathogenic microorganisms (Escherichia coli, Pseudomonas aeruginosa, Listeria monocytogenes, Staphylococcus aureus, and Candida albicans). The minimum effective concentration of the bioaugmented substance for organic, inorganic and microbial pollutants removal from high strength wastewater was 2.5 ppm with a contact time of 6-8 h. The removal efficiencies of H 2 S, COD, BOD 5 , total solids (TS), total dissolved solids, total suspended solids, ammonia, nitrate, phosphorus, and oil and grease reached 85, 93.4, 83.5, 37, 49.2, 93.4, 100, 55.7, 76.6 and 76.6%, respectively in the treated effluent after sand biofiltration. The physicochemical parameters of the treated wastewater effluent were below the Egyptian recommended limits (Law 84/1984) for use in irrigation. However, COD and BOD values were 90.33 and 38.46 mgO 2 /L, respectively, and were still above the regulations (COD ≤60 and BOD ≤20). The high fecal coliforms count in the wastewater influent (8.4 × 10 8 MPN-index/100 mL) were 95.1% removed after the sedimentation stage, and 99.99% removal was achieved after gravel and sand biofiltration. Thus, this study successfully designed a bioaugmented multistage biofiltration system for the effective removal of pollutants from wastewater, especially in resource-limited areas., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Sequential biofiltration (SBF) has been demonstrated to be a promising approach to achieve enhanced biological removal of various trace organic compounds (TOrCs) from wastewater treatment plant (WWTP) effluents by establishing oxic and carbon-limited conditions. This study investigated options to further advance the feasibility of SBF systems by reducing empty bed contact times (EBCTs). Additional experiments were conducted to investigate the pre-treatment of WWTP effluent by coagulation as an option to further decrease the organic carbon availability during SBF. Results indicated that an EBCT reduction in the first filter stage from 90 to 45 and 30 min adversely affected process performance regarding the removal of organic bulk parameters and several TOrCs over short-term. However, after an extended adaptation period of ten weeks comparable performance was observed in two SBF systems with first stage filters operated at EBCTs of 90 and 45 min. The pre-treatment of secondary effluent by coagulation, flocculation and sedimentation was not found to enhance the performance of an SBF system despite substantial removal of organic bulk parameters during the pre-treatment. However, despite the vast removal of total phosphorous during coagulation, nutrient limitation was not found to adversely affect the biological performance of the subsequent SBF system., (Copyright © 2019 Elsevier B.V. All rights reserved.)

An innovative biofiltration-ozonation-biofiltration process was established and applied for the treatment of oil sands process water (OSPW). With an equivalent hydraulic retention time (HRT) of 8 h, the biofiltration pretreatment removed 24.4% of classical naphthenic acids (NAs) and 3.3% of oxidized NAs from raw OSPW with removal rate of 0.4 mg/L/h and 0.1 mg/L. Oxidized NAs showed higher resistance to the biofiltration process than classical NAs. The mild ozonation process (with utilized ozone dose of 30 mg/L) removed 84.8% of classical NAs and 11.5% of oxidized NAs from the biofiltrated OSPW with a degradation efficiency of 0.3 mg classical NAs/mg O 3 and 0.1 mg oxidized NAs/mg O 3 . However, by using the same utilized ozone dose, the degradation of classical NAs and oxidized NAs from raw OSPW was 32.1% and 3.9% with ozonation efficiency of 0.1 mg classical NAs/mg O 3 and 0.0 mg oxidized NAs/mg O 3 , respectively. Compared with the biofiltration pretreatment, the post biofiltration process (with HRT of 8 h) showed higher degradation effect on oxidized NAs with removal ratio of 22.9% and removal rate of 0.4 mg/L/h, but showed lower degradation effect on classical NAs with removal ratio of 6.7% and removal rate of 0.0 mg/L/h. After biofiltration-ozonation-biofiltration treatment, the microbial community structure in the biofilter was investigated by next generation sequencing. Proteobacteria and Rhodococcus were dominant bacterial phyla and genus in the biofilter, the abundance of which were 47.21% and 9.50% which were different from those in raw OSPW (62.88% and 0.72%). The change of microbial community structure could be resulted from the interaction between microbial community and the circulating OSPW. The ozonation integrated biodegradation process removed 89.3% and 34.0% of classical and oxidized NAs from OSPW which shows high potential to be applied by the oil and gas industry., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Road runoff is contaminated by various micropollutants and may be treated using low impact development techniques, such as stormwater biofilters. Better understanding the processes, such as filtration, sorption and leaching, which affect pollutants in these systems is essential to reliably predicting treatment performance and optimizing system design. Field data from an in situ monitoring campaign, wherein dissolved and particulate concentrations of a wide range of micropollutants (trace metals, polycyclic aromatic hydrocarbons, bisphenol-A, alkylphenols and phthalates) were characterized in untreated road runoff and biofilter outlets for 19 rain events, are used to explore transport and retention processes. Although retention of the particulate phase of pollutants was generally quite effective, unusually high particle concentrations were observed at biofilter outlets for three winter events. Particle characterization in road runoff and outlet waters revealed that this degraded performance was due to poor filtration rather than particle erosion, which was attributed to the relative abundance of small (<10 μm) particles during this period, along with possible preferential flows. Dissolved pollutants were less effectively removed in general. To better understand this behavior, field results were combined with laboratory sorption and leaching tests. Dissolved concentrations of trace metals were shown to be influenced by organic carbon; leaching from road-originated particles may also influence their transport. Removal of the dissolved phase of organic micropollutants was limited by the contamination of the filter media, either before installation or during the first period of operation, due to emissions from construction materials., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Large volumes of water are required for the development of unconventional oil and gas (O&G) wells. Water scarcity coupled with seismicity induced by deep-well disposal promote new O&G wastewater management strategies, specifically treatment and reuse. One technology that has been proven effective for removal of organic matter and solids is biologically active filtration (BAF) with granular active carbon (GAC); however, further optimization is needed to enhance BAF performance. This study evaluated three GAC media (one spent and two new) and two nutrient-mix supplements for enhanced removal of chemical oxygen demand (COD) and dissolved organic carbon (DOC). Biofilm development was also monitored and correlated to BAF performance. The spent GAC with extant biofilm quickly acclimated to PW and demonstrated up to 92% DOC removal (81% COD) in 24h, while little impact by nutrient addition was observed. In addition, virgin GAC was slow to establish a biofilm, indicating that appropriate GAC selection and pre-developed biofilm is critical for efficient BAF performance. Furthermore, the production of high quality BAF effluent (less than 20mg/L DOC) presents the opportunity to apply BAF as a pretreatment for subsequent desalination-expanding the potential for reuse applications of PW., (Copyright © 2017. Published by Elsevier B.V.)

Dissolved organic matter (DOM) present in oil and gas (O&G) produced water and fracturing flowback was characterized and quantified by multiple analytical techniques throughout a hybrid biological-physical treatment process. Quantitative and qualitative analysis of DOM by liquid chromatography - organic carbon detection (LC-OCD), liquid chromatography-high-resolution mass spectrometry (LC-HRMS), gas chromatography-mass spectrometry (GC-MS), and 3D fluorescence spectroscopy, demonstrated increasing removal of all groups of DOM throughout the treatment train, with most removal occurring during biological pretreatment and some subsequent removal achieved during membrane treatment. Parallel factor analysis (PARAFAC) further validated these results and identified five fluorescent components, including DOM described as humic acids, fulvic acids, proteins, and aromatics. Tryptophan-like compounds bound by complexation to humics/fulvics were most difficult to remove biologically, while aromatics (particularly low molecular weight neutrals) were more challenging to remove with membranes. Strong correlation among PARAFAC, LC-OCD, LC-HRMS, and GC-MS suggests that PARAFAC can be a quick, affordable, and accurate tool for evaluating the presence or removal of specific DOM groups in O&G wastewater., (Copyright © 2017 Elsevier B.V. All rights reserved.)

Particulate wastes derived from cage fish farming are a trophic resource used by wild fish. This study assesses waste consumption by wild fish and the impact on the final balance of wastes. Consumption was determined according to the difference between the particulate matter exiting the cages and that reaching 5 m away at three different depths, in the presence and absence of wild fish. Wild fish around the experimental cages were counted during feeding and non-feeding periods. A weighted abundance of 1057 fish 1000 m -3 consumed 17.75% of the particulate wastes exiting the cages, on average. Consumption was higher below the cages, where waste outflow was greater. However, waste removal by wild fish was noteworthy along the shallow and deep sides of the cages. Wild fish diminished the net particulate wastes by about 14%, transforming them into more easily dispersible and less harmful wastes. This study demonstrates the mitigating potential of wild fish in reducing environmental impact., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

In this study, nitrous oxide (N2O) emissions from a full-scale denitrifying biofilter plant were continuously monitored over two periods (summer campaign in September 2014 and winter campaign in February 2015). Results of the summer campaign showed that the major part (>99%) of N2O flux was found in the liquid phase and was discharged with the effluent. N2O emissions were highly variable and represented in average 1.28±1.99% and 0.22±0.31% of the nitrate uptake rate during summer and winter campaigns, respectively. Denitrification was able to consume a large amount of dissolved N2O coming from the upstream nitrification stage. In the absence of methanol injection failure and with an influent BOD/NO3-N ratio higher than 3, average reduction of N2O was estimated to be of 93%. The control of exogenous carbon dosage is essential to minimize N2O production from denitrifying biofilters, in correlation to NO2-N concentrations in the filter., (Copyright © 2016 Elsevier B.V. All rights reserved.)

The presence of endocrine disrupting compounds (EDCs), pharmaceutically active compounds (PhACs) and artificial sweeteners are of concern to water providers because they may be incompletely removed by wastewater treatment processes and they pose an unknown risk to consumers due to long-term consumption of low concentrations of these compounds. This study utilized pilot-scale conventional and biological drinking water treatment processes to assess the removal of nine PhACs and EDCs, and two artificial sweeteners. Conventional treatment (coagulation, flocculation, settling, non-biological dual-media filtration) was compared to biofilters with or without the addition of in-line coagulant (0.2-0.8 mg Al(3+)/L; alum or PACl). A combination of biofiltration, with or without in-line alum, and conventional filtration was able to reduce 7 of the 9 PhACs and EDCs by more than 50% from river water while artificial sweeteners were inconsistently removed by conventional treatment or biofiltration. Increasing doses of PACl from 0 to 0.8 mg/L resulted in average removals of PhACs, EDCs increasing from 39 to 70% and artificial sweeteners removal increasing from ~15% to ~35% in lake water. These results suggest that a combination of biological, chemical and physical treatment can be applied to effectively reduce the concentration of EDCs, PhACs, and artificial sweeteners., (Copyright © 2015 Elsevier B.V. All rights reserved.)

The fate of pharmaceutically active compounds (PhACs) in wastewater treatment systems is an area of increasing concern. Little research has been done to understand this issue in rural or decentralized communities. The objective of this research was to examine the ability of a bench scale nitrifying recirculating biofilter (RBF) to remove four acidic PhACs: gemfibrozil, naproxen, ibuprofen and diclofenac from secondary treated municipal wastewater at concentrations of 20 and 200μg/L. The average removals in this study were between 92 and 99% for ibuprofen, 89 and 99% for naproxen, 62 and 92% for gemfibrozil and 40 and 76% for diclofenac, which is consistent with literature. Ibuprofen and naproxen were largely removed through biological transformation; whereas gemfibrozil and diclofenac showed more variable removal, likely due to both biological transformation and sorption processes. PhAC removal in the RBFs was repeatable between trials, robust and responsive to system upsets, and the presence of PhACs as a single compound versus mixtures had no impact on PhAC removal efficiency. In summary, this study indicates that RBFs as a nitrifying stage of a multi-stage filtration process could be a viable technology for removal of some acidic pharmaceuticals in small onsite wastewater treatment facilities., (Copyright © 2014 Elsevier B.V. All rights reserved.)

A formaldehyde airstream was treated in a biofilter for an extended period of time. During the first 133 days, the reactor was operated without ozone, whereas over the following 82 days ozone was intermittently implemented. The maximum stable elimination capacity obtained without ozone was around 57 g m(-3) h(-1). A greater load could not be treated under these conditions, and no significant formaldehyde removal was maintained for inlet loads greater than 65 g m(-3) h(-1); the activity of microorganisms was then inhibited by the presence of acidic byproducts, and the media acidified (pH<4). The implementation of ozone pulses allowed a stable elimination capacity to be obtained, even at greater loads (74 g m(-3) h(-1)). The effect of ozone on the extra cellular polymeric substances detachment from the biofilm could not be confirmed due to the too low biofilter biomass content. Thus, the results suggest that ozone acted as an in situ pH regulator, preventing acidic byproducts accumulation, and allowing the treatment of high loads of formaldehyde., (Copyright © 2013 Elsevier B.V. All rights reserved.)