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1. Stereocontrolled synthesis of lankanolide from 1,6-anhydro-beta-D-glucopyranose (levoglucosan): 1, synthesis of the C-1/7 and C-8/15 segments.

Author

Kochetkov NK, Yashunsky DV, Sviridov AF, and Ermolenko MS

Subjects
Chemical Phenomena, Chemistry, Macrolides, Stereoisomerism, Anti-Bacterial Agents chemical synthesis, Lactones chemical synthesis
Abstract

A scheme has been designed for the stereocontrolled synthesis of lankanolide, the aglycon of lankamycin. Synthesis of its C-1/7 and C-8/15 segments has been accomplished starting from 1,6-anhydro-2,4-dideoxy-2,4-di-C-methyl-beta-D-glucopyranose.

Published
1990
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