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The established practices of intensive agriculture, combined with inadequate soil Κ replenishment by conventional inorganic fertilization, results in a negative environmental impact through the gradual exhaustion of different forms of K reserves in soils. Although biochar application as soil amendment has been established as an approach of integrated nutrient management, few works have focused on the impact of biochar application to soil K availability and crop uptake. This review provides an up-to-date analysis of the published literature, focusing on the impact of biochar in the availability of potassium in soil and crop growth. First, the effect of biomass type and pyrolysis temperature on potassium content of biochar was assessed. Second, the influence of biochar addition to the availability of potassium in soil and on potassium soil dynamics was examined. Finally, alternative methods for estimating available K in soils were proposed. The most promising biomasses in terms of potassium content were grape pomace, coffee husk and hazelnut husk however, these have not been widely utilized for biochar production. Higher pyrolysis temperatures (>500 °C) increase the total potassium content whereas lower temperatures increase the water-soluble and exchangeable potassium fractions. It was also determined that biochar has considerable potential for enhancing K availability through several distinct mechanisms which eventually lead directly or indirectly to increased K uptake by plants. Indirect mechanisms mainly include increased K retention capacity based on biochar properties such as high cation exchange capacity, porosity, and specific surface area, while the direct supply of K can be provided by K-rich biochar sources through purpose-made biochar production techniques. Research based on biochar applications for soil K fertility purposes is still at an early stage, therefore future work should focus on elucidating the mechanisms that define K retention and release processes through the complicated soil-biochar-plant system., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

In the present study we investigated the sorption behavior of Cs in four different soils (sandyloam, loam, clayloam and clay) by using batch experiment. Cs sorption characteristics of the studied soils were examined at 4 mgL(-1) Cs concentration, at various pH levels, at room temperature and with 0.01 M CaCl(2) as a background electrolyte. Among different soils the decrease of k(d) (distribution coefficient) of cesium, at all pH levels, followed the sequence sandyloam > loam > clayloam > clay, indicating that the particle size fractions and especially the clay content plays predominant role on sorption of Cs. The effect of pH on cesium sorption displays a similar pattern for all soils, depending on soil type. At acid pH levels less cesium was sorbed, due to a greater competition with other cations for available sorption sites. The maximum sorption of Cs was observed at pH 8, where the negative charge density on the surface of the absorbents was the highest. For all soils was observed significantly lower Cs sorption at pH 10.