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Bromobenzoquinones and 2,4,6-tribromophenol belong to disinfection or chlorination by-products than can be formed in bromide-rich waters during chlorination or chloramination. Due to their high toxicities, sensitive and cost-effective analytical methods are necessary to detect and quantify them in various environmental matrices. A determination method of 2,5-dibromo-1,4-benzoquinone, 2,6-dibromo-3,5-dimethyl-1,4-benzoquinone, 2,6-dibromo-3-chloro-5-methyl-1,4-benzoquinone, 2,3,5,6-tetrabromo-1,4-benzoquinone and, 2,4,6-tribromophenol was developed using solid-phase extraction and electron capture detector-gas chromatography separation and detection (SPE-GC-ECD). Preservation of the four bromobenzoquinones with ascorbic acid allow to stabilize them into their bromohydroquinone analogues and to quench residual chlorine. Efficiency of different sorbents was tested and extraction and elution parameters were optimized by use of an experimental design. The recovery rates of each of the five compounds studied were between 59 and 101.4 %. The limits of detection (LODs) of the SPE-GC-ECD method were between 7 and 22 ng L−1. Applying this analytical procedure to real industrial chlorinated discharges in seawater, we report for the first time the presence of 2,6-dibromo-3- chloro-5-methyl-1,4-benzoquinone (up to 47 ng L−1), 2,6-dibromo-3,5-dimethyl-1,4-benzoquinone (35 ng L−1) and 2,4,6-tribromophenol (up to 42 ng L−1) in such effluents.

In the Mediterranean area, surface waters often have low discharge or renewal rates, hence metal contamination from industrialised catchments can have a high negative impact on the physico-chemical and biological water quality. In a context of climate and anthropological changes, it is necessary to provide an integrative approach for the prevention and control of metal pollution, in order to limit its impact on water resources, biodiversity, trophic network and human health. For this purpose, introduction of constructed wetlands (CWs) between natural aquatic ecosystems and industrialised zones or catchments is a promising strategy for eco-remediation. Analysis of the literature has shown that further research must be done to improve CW design, selection and management of wetland plant species and catchment organisation, in order to ensure the effectiveness of CWs in Mediterranean environments. Firstly, the parameters of basin design that have the greatest influence on metal removal processes must be identified, in order to better focus rhizospheric processes on specific purification objectives. We have summarised in a single diagram the relationships between the design parameters of a CW basin and the physico-chemical and biological processes of metal removal, on the basis of 21 mutually consistent papers. Secondly, in order to optimise the selection and distribution of helophytes in CWs, it is necessary to identify criteria of choice for the plant species that will best fit the remediation objectives and environmental and economic constraints. We have analysed the factors determining plant metal uptake efficiency in CWs on the basis of a qualitative meta-analysis of 13 studies with a view to determine whether the part played by metal uptake by plants is relevant in comparison with the other removal processes. Thirdly, we analysed the parameters to consider for establishing suitable management strategies for CWs and how they affect the whole CW design process. Finally, we propose monitoring and policy measures to facilitate the integration of CWs within Mediterranean industrialised catchments. Keywords: Constructed wetlands, Metal pollution, Plant species selection, Design methodologies, Management strategies, Industrialized Mediterranean Catchments