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Mesoporous silica (MCM-41) is widely used as a supporting material due to its large specific surface area and good stability, but it cannot remove heavy metals due to the lack of adsorption active sites. In this study, the MCM-41 (a mesoporous SiO 2 material) decorated with iron and magnesium oxide (Fe/Mg-MCM-41) was found to be an excellent adsorbent to remove arsenic(V) from water. FTIR, BET, TEM-EDS, XRD, XPS, etc. were applied for characterization analysis. Adsorption isotherms were fitted well by the Langmuir model and the experimental maximum adsorption capacity of Fe/Mg 4 -MCM-41 (magnesium accounts for 4%) was 71.53 mg/g at pH = 3. Thermodynamics analysis suggested exothermic nature of adsorption behavior. Kinetic process was well described by the pseudo-second-order model and adsorption rate was controlled by intraparticle diffusion and film diffusion. Moreover, the adsorption behavior of As(V) onto Fe/Mg 4 -MCM-41 was investigated under different reaction conditions, such as pH, temperature, Mg-doping and competing ions. The results showed that loading a certain amount of magnesium can significantly improve arsenic removal efficiency. Additionally, Fe/Mg 4 -MCM-41 exhibits high arsenic(V) removal in the wide pH range of 3-10. The Fe/Mg 4 -MCM-41 can be regenerated and used after four consecutive cycles. The high arsenic(V) sorption capacity, wide range of pH applications, ability to regenerate, and reusability of Fe/Mg 4 -MCM-41 confirmed that this adsorbent is promising for treating As-contaminated wastewater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Biochar is becoming an environmentally friendly material for remediation of heavy metal contaminated soils and improving food safety. A field trial over four rice seasons was conducted to investigate the use of biochar and low Cd accumulating cultivars on Cd uptake in a heavy metal contaminated soil. Wheat straw derived biochar was applied at 0, 20 and 40 t ha(-1). Two rice cultivars with differing Cd accumulation abilities were selected in each season. The results showed that both biochar and low Cd affinity cultivars significantly reduced rice grain Cd accumulation. Biochar had no significant effect the first season but thereafter consistently reduced rice grain Cd by a maximum of 61, 86 and 57% over the next three seasons. Zn accumulation in the rice grains was not decreased by biochar application, although available soil Zn was sharply reduced (35-91%). Indica conventional rice cultivars had much lower Cd, but higher Zn and lower Cd/Zn ratios in the grain than indica hybrid cultivars. Biochar was more effective for mitigating grain Cd accumulation in low Cd affinity cultivars than in high affinity cultivars. Soil pH was sustainably increased (up to nearly 1 unit) while available Cd significantly decreased by a maximum of 85% after biochar addition. The translocation of Cd from rice roots to shoots was reduced from 20 to 80% by biochar. Low uptake affinity cultivars combined with biochar reduced late rice grain Cd concentration and Cd/Zn ratios by 69-80% and 72-80%, respectively. It indicated that the management of combining biochar and low Cd affinity cultivars should be an efficient way to remediate Cd contaminated rice paddies and reduce health risk associated with consuming rice from these soils., (Copyright © 2015 Elsevier B.V. All rights reserved.)